Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide
The gas-phase photolysis of isopropyl iodide with light of wavelengths ≥3130 Å has been reinvestigated. In presence of mercury the only source of propene is the disproportionation of the isopropyl radicals. A value of 0·58 ± 0·04 was obtained for the combination- disproportionation ratio of the isop...
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| Otros Autores: | , |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
1967
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 02225caa a22003137a 4500 | ||
|---|---|---|---|
| 001 | PAPER-1629 | ||
| 003 | AR-BaUEN | ||
| 005 | 20241101092735.0 | ||
| 008 | 190411s1967 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-37049117128 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Braslavsky, Silvia Elsa | |
| 245 | 1 | 0 | |a Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide |
| 260 | |c 1967 | ||
| 270 | 1 | 0 | |m Braslavsky, S.E.; Departamento di Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Buenos Aires, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a The gas-phase photolysis of isopropyl iodide with light of wavelengths ≥3130 Å has been reinvestigated. In presence of mercury the only source of propene is the disproportionation of the isopropyl radicals. A value of 0·58 ± 0·04 was obtained for the combination- disproportionation ratio of the isopropyl radicals, in agreement with values given in the literature. This shows that alkyl iodides can be a useful source of free radicals. |l eng | |
| 593 | |a Departamento di Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Buenos Aires, Argentina | ||
| 593 | |a Universidad Técnica del Estado, Laboratorio Central de Química, Santiago, Chile | ||
| 700 | 1 | |a Grotewold, J. | |
| 700 | 1 | |a Lissi, E.A. | |
| 773 | 0 | |d 1967 |h pp. 414-415 |x 00456470 |w (AR-BaUEN)CENRE-2394 |t Journal of the Chemical Society B: Physical Organic | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-37049117128&doi=10.1039%2fJ29670000414&partnerID=40&md5=10541228c72858eab9637628f2ba0b8c |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1039/J29670000414 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00456470_v_n_p414_Braslavsky |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00456470_v_n_p414_Braslavsky |y Registro en la Biblioteca Digital |
| 961 | |a paper_00456470_v_n_p414_Braslavsky |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 62582 | ||