Vapor-Phase Hydrogenolysis of Glycerol to 1,2-Propanediol over Cu/Al2O3 Catalyst at Ambient Hydrogen Pressure
In this paper, we report that the hydrogenolysis of glycerol can be carried out at atmospheric pressure and low temperature with high selectivity to 1,2-propanediol (1,2-PDO) over reduced copper catalyst. The vapor-phase reaction was carried out over the copper-based catalysts supported on alumina a...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
American Chemical Society
2016
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 10504caa a22009737a 4500 | ||
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| 001 | PAPER-16138 | ||
| 003 | AR-BaUEN | ||
| 005 | 20240927142704.0 | ||
| 008 | 190411s2016 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84960364845 | |
| 030 | |a IECRE | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Dieuzeide, M.L. | |
| 245 | 1 | 0 | |a Vapor-Phase Hydrogenolysis of Glycerol to 1,2-Propanediol over Cu/Al2O3 Catalyst at Ambient Hydrogen Pressure |
| 260 | |b American Chemical Society |c 2016 | ||
| 270 | 1 | 0 | |m Amadeo, N.; ITHES, UBA, CONICET, Laboratorio de Procesos Catalíticos, Departamento de Ing. Química, Facultad de Ingeniería, Universidad de Buenos Aires, Pabellón de Industrias, Ciudad UniversitariaArgentina; email: norma@di.fcen.uba.ar |
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| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a In this paper, we report that the hydrogenolysis of glycerol can be carried out at atmospheric pressure and low temperature with high selectivity to 1,2-propanediol (1,2-PDO) over reduced copper catalyst. The vapor-phase reaction was carried out over the copper-based catalysts supported on alumina at ambient pressure, and the effects of temperature, space time, and H2 molar fraction in the feed were analyzed. The textural and structural characteristics of the catalysts with increasing copper loading were determined by N2 sorptometry (BET), inductively coupled plasma-atomic spectroscopy (ICP-AES), powder X-ray diffraction (PXRD), temperature-programmed reduction (TPR), and N2O chemisorption (metallic area). On the basis of both characterization and activity results, it was possible to conclude that the hydrogenolysis of glycerol to 1,2-propanediol in vapor phase at atmospheric pressure over copper-based catalysts is a structure sensitive reaction. Activity results suggests that the most probable pathway for the glycerol conversion into 1,2-propanediol under the employed conditions is glycerol is dehydration to hydroxyacetone (acetol), followed by its hydrogenation into 1,2-propanediol. Complete glycerol conversion and a selectivity of 60% to 1,2-propanediol was achieved, using a catalyst with 15 wt % CuO at 200°C, H2 molar fraction of 61%, and atmospheric pressure. © 2016 American Chemical Society. |l eng | |
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: We thank UBA and CONICET for the financial support. | ||
| 593 | |a ITHES, UBA, CONICET, Laboratorio de Procesos Catalíticos, Departamento de Ing. Química, Facultad de Ingeniería, Universidad de Buenos Aires, Pabellón de Industrias, Ciudad Universitaria, Ciudad Autónoma de Buenos Aires, 1428, Argentina | ||
| 593 | |a INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria, Ciudad Autónoma de Buenos Aires, 1428, Argentina | ||
| 690 | 1 | 0 | |a ALUMINA |
| 690 | 1 | 0 | |a ATMOSPHERIC PRESSURE |
| 690 | 1 | 0 | |a ATMOSPHERIC STRUCTURE |
| 690 | 1 | 0 | |a ATMOSPHERIC TEMPERATURE |
| 690 | 1 | 0 | |a ATOMIC EMISSION SPECTROSCOPY |
| 690 | 1 | 0 | |a ATOMIC SPECTROSCOPY |
| 690 | 1 | 0 | |a CATALYSTS |
| 690 | 1 | 0 | |a COPPER |
| 690 | 1 | 0 | |a GLYCEROL |
| 690 | 1 | 0 | |a HYDROGENOLYSIS |
| 690 | 1 | 0 | |a HYDROLYSIS |
| 690 | 1 | 0 | |a INDUCTIVELY COUPLED PLASMA |
| 690 | 1 | 0 | |a TEMPERATURE |
| 690 | 1 | 0 | |a VAPOR PHASE EPITAXY |
| 690 | 1 | 0 | |a X RAY DIFFRACTION |
| 690 | 1 | 0 | |a COPPER-BASED CATALYSTS |
| 690 | 1 | 0 | |a EFFECTS OF TEMPERATURE |
| 690 | 1 | 0 | |a GLYCEROL CONVERSIONS |
| 690 | 1 | 0 | |a POWDER X-RAY DIFFRACTION (PXRD) |
| 690 | 1 | 0 | |a STRUCTURAL CHARACTERISTICS |
| 690 | 1 | 0 | |a STRUCTURE SENSITIVE REACTIONS |
| 690 | 1 | 0 | |a TEMPERATURE-PROGRAMMED REDUCTION |
| 690 | 1 | 0 | |a VAPOR PHASE REACTIONS |
| 690 | 1 | 0 | |a CATALYST SELECTIVITY |
| 700 | 1 | |a Jobbagy, M. | |
| 700 | 1 | |a Amadeo, Norma Elvira | |
| 773 | 0 | |d American Chemical Society, 2016 |g v. 55 |h pp. 2527-2533 |k n. 9 |p Ind. Eng. Chem. Res. |x 08885885 |w (AR-BaUEN)CENRE-316 |t Industrial and Engineering Chemistry Research | |
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