Evaluation of solvents used in summarized chromatograms

Based on some concepts from the Information Theory, the solvents used for antibiotic substances by Ishida etal and Betina were evaluated relative to each other by means of summarized chromatography. The information that a summarized chromatogram system supplies should depend mainly on three factors:...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autor principal: Souto, J.
Otros Autores: De Valesi, A.G
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1970
Acceso en línea:Registro en Scopus
DOI
Handle
Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
LEADER 04137caa a22006257a 4500
001 PAPER-1565
003 AR-BaUEN
005 20230518203055.0
008 190411s1970 xx ||||fo|||| 00| 0 eng|d
024 7 |2 scopus  |a 2-s2.0-0014931885 
024 7 |2 cas  |a benzene, 71-43-2; water, 7732-18-5; Alcohols; Antibiotics; Benzene, 71-43-2; Phenols; Solvents; Water, 7732-18-5 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
030 |a JCRAE 
100 1 |a Souto, J. 
245 1 0 |a Evaluation of solvents used in summarized chromatograms 
260 |c 1970 
270 1 0 |m Souto, J.; Equipo de Antibióticos y Factores de Crecimiento, Instituto de Microbiologia e Industrias Agropecuarias, I.N.T.A. Buenos AiresArgentina 
506 |2 openaire  |e Política editorial 
504 |a Ishida, Shiratori, Okamoto, (1950) J. Antibiotics (Tokyo), Ser. A, 3, p. 880 
504 |a Betina, (1964) J. Chromatog., 15, p. 379 
504 |a Connors, Correlation and Prediction of Solvent Effects on Paper Chromatographic Rfvalues (1965) Analytical Chemistry, 37, p. 261 
504 |a Soczewinski, Correlation of RMValues in Pairs of Paper Chromatographic Partition Systems (1965) Analytical Chemistry, 37, p. 439 
504 |a Shannon, Weaver, (1949) The Mathematical Theory of Communication, , Univ. of Illinois Press, Urbana 
504 |a Eilberg, Souto, (1966) Rev. Invest. Agrop., 3, p. 43 
504 |a Feller, (1957) An Introduction in Probability Theory and its Applications, , Wiley, New York 
520 3 |a Based on some concepts from the Information Theory, the solvents used for antibiotic substances by Ishida etal and Betina were evaluated relative to each other by means of summarized chromatography. The information that a summarized chromatogram system supplies should depend mainly on three factors: (1) distribution of the R F of the reference substances in each solvent; (2) interrelationship between the R F values that a given substance shows in the different solvents; and (3) experimental error. Thus, admitting a constant error, it was found that among the 11 solvents tested, those that gave the most information were water; butanol; 3% aq. ammonium chloride; benzene-methanol (4:1) and butanol-methanol-water (4:1:2) with and without helianthin. The phenolic solvents were less informative; ethyl acetate is mediocre in all cases. Although the information is very high in some of the 11 solvents tested (up to 85% of H max ), only water supplies information independent of the others, which are redundant among each other. © 1970.  |l eng 
593 |a Equipo de Antibióticos y Factores de Crecimiento, Instituto de Microbiologia e Industrias Agropecuarias, I.N.T.A. Buenos Aires, Argentina 
593 |a Departamento de Biología, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Argentina 
690 1 0 |a ALCOHOL DERIVATIVE 
690 1 0 |a ANTIBIOTIC AGENT 
690 1 0 |a BENZENE 
690 1 0 |a PHENOL DERIVATIVE 
690 1 0 |a SOLVENT 
690 1 0 |a WATER 
690 1 0 |a ARTICLE 
690 1 0 |a CHROMATOGRAPHY 
690 1 0 |a FUNGUS 
690 1 0 |a ALCOHOLS 
690 1 0 |a ANTIBIOTICS 
690 1 0 |a BENZENE 
690 1 0 |a CHROMATOGRAPHY 
690 1 0 |a FUNGI 
690 1 0 |a PHENOLS 
690 1 0 |a SOLVENTS 
690 1 0 |a WATER 
700 1 |a De Valesi, A.G. 
773 0 |d 1970  |g v. 46  |h pp. 274-279  |k n. C  |p J. Chromatogr. A  |x 00219673  |w (AR-BaUEN)CENRE-1093  |t Journal of Chromatography A 
856 4 1 |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-0014931885&doi=10.1016%2fS0021-9673%2800%2983998-9&partnerID=40&md5=d280d56121753ae02f56aea571d807e1  |y Registro en Scopus 
856 4 0 |u https://doi.org/10.1016/S0021-9673(00)83998-9  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_00219673_v46_nC_p274_Souto  |y Handle 
856 4 0 |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219673_v46_nC_p274_Souto  |y Registro en la Biblioteca Digital 
961 |a paper_00219673_v46_nC_p274_Souto  |b paper  |c PE 
962 |a info:eu-repo/semantics/article  |a info:ar-repo/semantics/artículo  |b info:eu-repo/semantics/publishedVersion 
963 |a VARI 
999 |c 62518