The photoconversion R-CH3 → R-CHO in indazole derivatives

The UV irradiation of 1-(p-nitrophenyl)-3-methyl-indazole leads to the formation of the corresponding 3-formyl derivative as product of the photooxidation R-CH3 → R-CHO. This method was applied to a series of substituted indazoles and the same reaction was observed with methyl groups attached to the...

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Autor principal: Land, H.B
Otros Autores: Frasca, A.R
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1970
Acceso en línea:Registro en Scopus
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100 1 |a Land, H.B. 
245 1 4 |a The photoconversion R-CH3 → R-CHO in indazole derivatives 
260 |c 1970 
270 1 0 |m Land, H.B.; Departmento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Perú, 222 Buenos Aires, Argentina 
506 |2 openaire  |e Política editorial 
504 |a Land, Frasca, (1969) Chem. & Ind., p. 1594 
504 |a Land, Frasca, (1970) Chem. & Ind., p. 500 
504 |a H. B. Land and A. R. Frasca, Organic Preparations and Procedures, in press; Hock, Lang, Autoxydation von Kohlenwasserstoffen, VI. Mitteil. : Über Indan-peroxyd (1942) Berichte der deutschen chemischen Gesellschaft (A and B Series), 75, p. 1051 
504 |a Hock, Lang, Autoxydation von Kohlenwasserstoffen, VII. Mitteil.: über Peroxyde einfacher Benzolkohlenwasserstoffe (1943) Berichte der deutschen chemischen Gesellschaft (A and B Series), 76, p. 169 
504 |a Hock, Lang, Autoxydation von Kohlenwasserstoffen, IX. Mitteil.: Über Peroxyde von Benzol-Derivaten (1944) Berichte der deutschen chemischen Gesellschaft (A and B Series), 77, p. 257 
504 |a Ciamician, Silber, Chemische Lichtwirkungen. XXII. Autooxydationen. I (1912) Berichte der deutschen chemischen Gesellschaft, 45, p. 38 
504 |a John, Behmel, Photochemische Oxydation des α-Picolins. (1933) Berichte der deutschen chemischen Gesellschaft (A and B Series), 66, p. 426 
504 |a John, Behmel, Chinolinderivate, IX.: Photochemische Oxydation methylierter 2-Phenyl-chinoline. (1933) Berichte der deutschen chemischen Gesellschaft (A and B Series), 66, p. 844 
504 |a Grajgar, Leach, (1961) C.r. Acad. Sci., Paris, 252, p. 3577 
504 |a Wei, Adelman, (1969) Tetrahedron Letters, 38, p. 3297 
504 |a Yates, Mackay, Garneau, (1968) Tetrahedron Letters, 52, p. 5389 
504 |a Tiefenthaler, Dörscheln, Göth, Schmid, (1967) Helv. Chim. Acta, 14, p. IX 
504 |a Tiefenthaler, Dörscheln, Göth, Schmid, Photoisomerisierung von Pyrazolen und Indazolen zu Imidazolen bzw. Benzimidazolen und 2-Amino-benzonitrilen (1967) Helvetica Chimica Acta, 14, p. 2244 
504 |a Hawkins, (1961) Organic Peroxides. Their Formation and Reactions, , Spon, London 
504 |a Schenck, Becker, Schulte-Elte, Krauch, Mit Benzophenon photosensibilisierte Autoxydation von sek. Alkoholen und Äthern. Darstellung von α-Hydroperoxyden (1963) Chemische Berichte, 96, p. 509 
504 |a Dennler, Frasca, (1966) Tetrahedron, 22, p. 3131 
504 |a C. R. Portal and A. R. Frasca, Anales Asoc. Quim. Argentina, in press 
520 3 |a The UV irradiation of 1-(p-nitrophenyl)-3-methyl-indazole leads to the formation of the corresponding 3-formyl derivative as product of the photooxidation R-CH3 → R-CHO. This method was applied to a series of substituted indazoles and the same reaction was observed with methyl groups attached to the pyrazole and to the benzene ring of the indazole. © 1970.  |l eng 
536 |a Detalles de la financiación: Philips 
536 |a Detalles de la financiación: Acknowledgements-The authors are grateful to Dr. V. Deulofeu for his interest in this work. to Mr J. Ferrer for the spectroscopic determmations. to Philips Argentina S.A. for a gift and to the Consejo National de lnvestigaciones Cientilicas y TCcnicas for a grant 
593 |a Departmento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Perú, 222 Buenos Aires, Argentina 
700 1 |a Frasca, A.R. 
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856 4 0 |u https://doi.org/10.1016/0040-4020(70)80018-7  |y DOI 
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