Spray-casting ABPBI membranes for high temperature PEM fuel cells
The preparation and characterization of membranes of poly[2,5-benzimidazole] (ABPBI) by spray casting at room temperature from an ethanol solution is described. The prepared membranes doped with 11 M H3PO4 sorbed 1.5 molecules of acid per imidazole ring exhibiting a proton conductivity of 0.05 S · c...
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Electrochemical Society Inc.
2017
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 10362caa a22012017a 4500 | ||
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| 001 | PAPER-15431 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518204610.0 | ||
| 008 | 190410s2017 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-85020924244 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a JESOA | ||
| 100 | 1 | |a Viva, F. | |
| 245 | 1 | 0 | |a Spray-casting ABPBI membranes for high temperature PEM fuel cells |
| 260 | |b Electrochemical Society Inc. |c 2017 | ||
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a The preparation and characterization of membranes of poly[2,5-benzimidazole] (ABPBI) by spray casting at room temperature from an ethanol solution is described. The prepared membranes doped with 11 M H3PO4 sorbed 1.5 molecules of acid per imidazole ring exhibiting a proton conductivity of 0.05 S · cm−1 at 153◦C. The 80 μm thick, homogeneous, membranes obtained were used for the preparation of a membrane electrode assembly (MEA). Fuel cell test conducted with the prepared MEA at temperatures between 100 and 180◦C shows an increase in the performance with temperature, with a maximum power density of 200 mW · cm−2 at 180◦C. The described ABPBI membrane preparation method from an ethanol solution at low temperature opens a simple route for overcoming the processability problems of the aforementioned polymer. © 2017 The Electrochemical Society. All rights reserved. |l eng | |
| 536 | |a Detalles de la financiación: PICT 00-2009 PRH 200-4 | ||
| 536 | |a Detalles de la financiación: Society for Experimental Mechanics | ||
| 536 | |a Detalles de la financiación: Universidad Nacional de Cuyo, SJ10/04 | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, PIP 095 | ||
| 536 | |a Detalles de la financiación: Health Research Council of New Zealand | ||
| 536 | |a Detalles de la financiación: The authors thank financial support from Agencia Nacional de Promoci?n Cient?fica y Tecnol?gica (ANPCyT) (PICT 00-2009 PRH 200-4), Consejo Nacional de Investigaciones Cient?ficas y Tecnol?gicas (CONICET, PIP 095) and Universidad Nacional de Gral. San Mart?n (UNSAM) (SJ10/04). Also, the authors thank to Chemistry Center and Superficial Processes Center from INTI institute for their helpful to fast availability of SEM and DRX equipments. MMB, HRC and FAV are staff members of CONICET. | ||
| 593 | |a Departamento de Física de la Materia Condensada, Gerencia de Investigaciones y Aplicaciones, Comisión Nacional de Energía Atómica (CNEA), Av. Gral. Paz 1499, Buenos Aires, B1650KNA, Argentina | ||
| 593 | |a Centro de Procesos Superficiales, Instituto Nacional de Tecnología Industrial (INTI), Av. Gral. Paz 5445B1650KNA, Argentina | ||
| 593 | |a Escuela de Ciencia y Tecnología, Universidad de Gral, Martín de Irigoyen 3100, San Martín, B1650KNA, Argentina | ||
| 593 | |a Instituto de Química Física de los Materiales, Medio Ambiente y Energía (INQUIMAE), Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria1428, Argentina | ||
| 690 | 1 | 0 | |a ETHANOL |
| 690 | 1 | 0 | |a ETHANOLAMINES |
| 690 | 1 | 0 | |a FUEL CELLS |
| 690 | 1 | 0 | |a MEMBRANES |
| 690 | 1 | 0 | |a ETHANOL SOLUTIONS |
| 690 | 1 | 0 | |a FUEL CELL TESTS |
| 690 | 1 | 0 | |a HIGH TEMPERATURE PEM FUEL CELLS |
| 690 | 1 | 0 | |a LOW TEMPERATURES |
| 690 | 1 | 0 | |a MAXIMUM POWER DENSITY |
| 690 | 1 | 0 | |a MEMBRANE ELECTRODE ASSEMBLIES |
| 690 | 1 | 0 | |a MEMBRANE PREPARATION |
| 690 | 1 | 0 | |a PROCESSABILITY |
| 690 | 1 | 0 | |a PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC) |
| 700 | 1 | |a Heredia, N. | |
| 700 | 1 | |a Palmbaum, S.P. | |
| 700 | 1 | |a Diaz, L. | |
| 700 | 1 | |a De Diego, J. | |
| 700 | 1 | |a Lozano, M. | |
| 700 | 1 | |a Bruno, M. | |
| 700 | 1 | |a Corti, H. | |
| 773 | 0 | |d Electrochemical Society Inc., 2017 |g v. 164 |h pp. F866-F872 |k n. 7 |p J Electrochem Soc |x 00134651 |w (AR-BaUEN)CENRE-38 |t Journal of the Electrochemical Society | |
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