Size effect of ZnO nanorods on physicochemical properties of plasticized starch composites
This work demonstrates that the size of ZnO nanorods (ZnONR) with similar aspect ratio determines several physicochemical and microbiological properties of thermoplastic starch composites (TPS/ZnONR) at a given concentration of ZnONRs. A combination of sol-gel and hydrothermal methods was developed...
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Elsevier Ltd
2017
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 15793caa a22012257a 4500 | ||
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| 001 | PAPER-15212 | ||
| 003 | AR-BaUEN | ||
| 005 | 20250423092505.0 | ||
| 008 | 190410s2017 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-85006149957 | |
| 030 | |a CAPOD | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Guz, L. | |
| 245 | 1 | 0 | |a Size effect of ZnO nanorods on physicochemical properties of plasticized starch composites |
| 260 | |b Elsevier Ltd |c 2017 | ||
| 270 | 1 | 0 | |m Candal, R.; Instituto de Investigación e Ingeniería Ambiental, CONICET, Universidad Nacional de San Martín, 25 de Mayo y Francia (1650), Argentina; email: rjcandal@gmail.com |
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| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a This work demonstrates that the size of ZnO nanorods (ZnONR) with similar aspect ratio determines several physicochemical and microbiological properties of thermoplastic starch composites (TPS/ZnONR) at a given concentration of ZnONRs. A combination of sol-gel and hydrothermal methods was developed to synthesize ZnONR with different sizes but similar aspect ratios. Starch composites containing 1 wt.% of ZnONR were prepared by casting. Composites with smaller size nanorods (ZnONR-S) showed more efficiency in shielding UVA radiation and had a higher solubility and water vapor permeability than those with larger nanorods (ZnONR-L). Mechanical properties, biodegradability and antibacterial activity were also influenced by the size of the ZnONR. X-ray diffraction analysis showed that composites with ZnONR-S maintained the typical B-V type starch structure, intensifying the V-type starch structure peaks, while composite with ZnONR-L induced the formation of an amorphous structure, preventing starch retrogradation during storage. Properties affected by nanorods size are fundamental in determining composite applications. © 2016 Elsevier Ltd |l eng | |
| 593 | |a Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales, Departamento de Física, Laboratorio de Polímeros y Materiales Compuestos (LPM&C), Instituto de Física de Buenos Aires (IFIBA-CONICET), Ciudad Universitaria (1428), Ciudad Autónoma de Buenos Aires, Argentina | ||
| 593 | |a Instituto de Investigación e Ingeniería Ambiental, CONICET, Universidad Nacional de San Martín, 25 de Mayo y Francia (1650), San Martín, Provincia de Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a BACTERICIDAL ACTIVITY |
| 690 | 1 | 0 | |a BIODEGRADABILITY |
| 690 | 1 | 0 | |a STARCH COMPOSITE |
| 690 | 1 | 0 | |a ZNO NANORODS SIZE |
| 690 | 1 | 0 | |a ASPECT RATIO |
| 690 | 1 | 0 | |a BIODEGRADABILITY |
| 690 | 1 | 0 | |a NANORODS |
| 690 | 1 | 0 | |a RADIATION SHIELDING |
| 690 | 1 | 0 | |a SOL-GELS |
| 690 | 1 | 0 | |a X RAY DIFFRACTION ANALYSIS |
| 690 | 1 | 0 | |a ZINC OXIDE |
| 690 | 1 | 0 | |a ANTI-BACTERIAL ACTIVITY |
| 690 | 1 | 0 | |a BACTERICIDAL ACTIVITY |
| 690 | 1 | 0 | |a COMPOSITE APPLICATIONS |
| 690 | 1 | 0 | |a PHYSICOCHEMICAL PROPERTY |
| 690 | 1 | 0 | |a STARCH COMPOSITES |
| 690 | 1 | 0 | |a STARCH RETROGRADATION |
| 690 | 1 | 0 | |a WATER VAPOR PERMEABILITY |
| 690 | 1 | 0 | |a ZNO NANOROD |
| 690 | 1 | 0 | |a STARCH |
| 700 | 1 | |a Famá, L. | |
| 700 | 1 | |a Candal, R. | |
| 700 | 1 | |a Goyanes, Silvia Nair | |
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