In-situ catalytic pyrolysis of peanut shells using modified natural zeolite
In-situ catalytic pyrolysis of peanut (Arachis hypogaea) shells was investigated employing modified clinoptilolite. Likewise, conventional pyrolysis of the shells was explored to quantify the deoxygenation degree of bio-oil. Two solid catalysts obtained from natural clinoptilolite were used: one whi...
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Elsevier B.V.
2017
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 12863caa a22011177a 4500 | ||
|---|---|---|---|
| 001 | PAPER-15007 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518204537.0 | ||
| 008 | 190410s2017 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-85010376014 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a FPTED | ||
| 100 | 1 | |a Gurevich Messina, L.I. | |
| 245 | 1 | 0 | |a In-situ catalytic pyrolysis of peanut shells using modified natural zeolite |
| 260 | |b Elsevier B.V. |c 2017 | ||
| 270 | 1 | 0 | |m Cukierman, A.L.; Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía − PINMATE, Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2620, Ciudad Universitaria, Argentina; email: analea@di.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a In-situ catalytic pyrolysis of peanut (Arachis hypogaea) shells was investigated employing modified clinoptilolite. Likewise, conventional pyrolysis of the shells was explored to quantify the deoxygenation degree of bio-oil. Two solid catalysts obtained from natural clinoptilolite were used: one which retained most of the native cations and another one subjected to ion exchange treatment to develop Brønsted acid sites. These catalysts were characterized using different techniques, such as scanning electron microscopy with X-ray microanalysis, Fourier transform infrared spectroscopy by pyridine adsorption, and nitrogen sorptometry. Assays in a bench scale installation based on a fixed bed reactor were conducted at 500 °C and the yields of the three kinds of pyrolysis products (bio-oil, bio-char and gases) were determined. Likewise, the composition and other physical properties of the bio-oil and gases were investigated. Both catalysts led to reduce the oxygen content of the bio-oil, improving its high heating value. On the other hand, catalytic pyrolysis promoted a slight reduction in bio-oil production at expenses of an increase in gases generation. The catalyst subjected to ion exchange performed better than the native form as less water was generated in the catalytic cracking. © 2017 Elsevier B.V. |l eng | |
| 536 | |a Detalles de la financiación: 2188 | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires, UBA 20020130100605BA | ||
| 536 | |a Detalles de la financiación: PIP 0183 | ||
| 536 | |a Detalles de la financiación: The authors gratefully acknowledge Agencia Nacional de Promoci?n Cient?fica y Tecnol?gica (ANPCYT?FONCYT PICT 2012?2188), Consejo Nacional de Investigaciones Cient?ficas y T?cnicas (CONICET PIP 0183), and Universidad de Buenos Aires (UBA 20020130100605BA) from Argentina, for financial support. | ||
| 593 | |a Programa de Investigación y Desarrollo de Fuentes Alternativas de Materias Primas y Energía − PINMATE, Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2620, Ciudad Universitaria, Buenos Aires, C1428BGA, Argentina | ||
| 593 | |a Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Godoy Cruz 2290, Buenos Aires, C1425FQB, Argentina | ||
| 593 | |a Cátedra de Tecnología Farmacéutica II, Departamento de Tecnología Farmacéutica, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Junín 956, Buenos Aires, C1113AAD, Argentina | ||
| 690 | 1 | 0 | |a BIO-OIL QUALITY IMPROVEMENT |
| 690 | 1 | 0 | |a CATALYTIC PYROLYSIS |
| 690 | 1 | 0 | |a CLINOPTILOLITE |
| 690 | 1 | 0 | |a PEANUT SHELLS |
| 690 | 1 | 0 | |a BIOFUELS |
| 690 | 1 | 0 | |a CATALYSTS |
| 690 | 1 | 0 | |a CHEMICAL REACTORS |
| 690 | 1 | 0 | |a FOURIER TRANSFORM INFRARED SPECTROSCOPY |
| 690 | 1 | 0 | |a ION EXCHANGE |
| 690 | 1 | 0 | |a OILSEEDS |
| 690 | 1 | 0 | |a PYROLYSIS |
| 690 | 1 | 0 | |a SCANNING ELECTRON MICROSCOPY |
| 690 | 1 | 0 | |a SHELLS (STRUCTURES) |
| 690 | 1 | 0 | |a ZEOLITES |
| 690 | 1 | 0 | |a BIO OIL |
| 690 | 1 | 0 | |a CATALYTIC PYROLYSIS |
| 690 | 1 | 0 | |a CLINOPTILOLITES |
| 690 | 1 | 0 | |a ION-EXCHANGE TREATMENT |
| 690 | 1 | 0 | |a MODIFIED CLINOPTILOLITE |
| 690 | 1 | 0 | |a NATURAL CLINOPTILOLITE |
| 690 | 1 | 0 | |a PEANUT SHELLS |
| 690 | 1 | 0 | |a PYRIDINE ADSORPTION |
| 690 | 1 | 0 | |a CATALYTIC CRACKING |
| 700 | 1 | |a Bonelli, P.R. | |
| 700 | 1 | |a Cukierman, A.L. | |
| 773 | 0 | |d Elsevier B.V., 2017 |g v. 159 |h pp. 160-167 |p Fuel Process Technol |x 03783820 |t Fuel Processing Technology | |
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