Chitin hybrid materials reinforced with graphene oxide nanosheets: Chemical and mechanical characterisation

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Chitin hybrid materials reinforced with graphene oxide nanosheets (nGO) have been prepared. The chitin : nGO ratio ranged from proportions where chitin was the main component to ones where nGO exceeded chitin. SEM and TEM images showed that high proportions of nGO may result in nanosheet association...

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Autor principal: González, J.A
Otros Autores: Mazzobre, M.F, Villanueva, M.E, Díaz, L.E, Copello, G.J
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Royal Society of Chemistry 2014
Acceso en línea:Registro en Scopus
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100 1 |a González, J.A. 
245 1 0 |a Chitin hybrid materials reinforced with graphene oxide nanosheets: Chemical and mechanical characterisation 
260 |b Royal Society of Chemistry  |c 2014 
270 1 0 |m Copello, G.J.; Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires (UBA), IQUIMEFA (UBA-CONICET), Junín 956, C1113AAD Buenos Aires, Argentina; email: gcopello@ffyb.uba.ar 
506 |2 openaire  |e Política editorial 
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520 3 |a Chitin hybrid materials reinforced with graphene oxide nanosheets (nGO) have been prepared. The chitin : nGO ratio ranged from proportions where chitin was the main component to ones where nGO exceeded chitin. SEM and TEM images showed that high proportions of nGO may result in nanosheet association. FTIR, 13C solid-state NMR and DSC analyses showed that the interaction among the components would not involve the formation of new molecular bonds. nGO was shown to act as a filler that induces structural rearrangements in chitin which lead to new hydrogen bonds among the chains. The mechanical stability proved to be higher when the nGO content in the hybrid was similar to or higher than that of chitin. The rheological behaviour of the material was shown to become more solid-like with increasing nGO content. The nGO did not interfere with lysozyme activity on chitin chains, indicating that these materials would be biodegradable. © 2014 the Partner Organisations.  |l eng 
593 |a Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires (UBA), IQUIMEFA (UBA-CONICET), Junín 956, C1113AAD Buenos Aires, Argentina 
593 |a Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires y CONICET, Intendente Guiraldes 2160, CP 1428, Buenos Aires, Argentina 
690 1 0 |a CHAINS 
690 1 0 |a GRAPHENE 
690 1 0 |a HYBRID MATERIALS 
690 1 0 |a HYDROGEN BONDS 
690 1 0 |a NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY 
690 1 0 |a REINFORCEMENT 
690 1 0 |a FTIR 
690 1 0 |a GRAPHENE OXIDE NANOSHEETS 
690 1 0 |a MECHANICAL CHARACTERISATION 
690 1 0 |a MOLECULAR BONDS 
690 1 0 |a RHEOLOGICAL BEHAVIOUR 
690 1 0 |a SEM AND TEM 
690 1 0 |a SOLID STATE NMR 
690 1 0 |a STRUCTURAL REARRANGEMENT 
690 1 0 |a CHITIN 
700 1 |a Mazzobre, M.F. 
700 1 |a Villanueva, M.E. 
700 1 |a Díaz, L.E. 
700 1 |a Copello, G.J. 
773 0 |d Royal Society of Chemistry, 2014  |g v. 4  |h pp. 16480-16488  |k n. 32  |p RSC Adv.  |x 20462069  |t RSC Advances 
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856 4 0 |u https://doi.org/10.1039/c3ra47986b  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_20462069_v4_n32_p16480_Gonzalez  |y Handle 
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999 |c 75353 

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