Highly efficient removal of Cr(VI) from water with nanoparticulated zerovalent iron: Understanding the Fe(III)-Cr(III) passive outer layer structure
Nanoscale zerovalent iron (nZVI) particles were successfully employed for Cr(VI) removal from aqueous solutions at pH 3. It was found that the capacity of the system increases with increasing nZVI dosage. Starting at 300. μM, a complete Cr(VI) conversion was achieved in 30. min with a Fe:Cr(VI) mola...
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2014
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| LEADER | 13279caa a22010337a 4500 | ||
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| 001 | PAPER-14232 | ||
| 003 | AR-BaUEN | ||
| 005 | 20250609093112.0 | ||
| 008 | 190411s2014 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84894330798 | |
| 030 | |a CMEJA | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Nahuel Montesinos, V. | |
| 245 | 1 | 0 | |a Highly efficient removal of Cr(VI) from water with nanoparticulated zerovalent iron: Understanding the Fe(III)-Cr(III) passive outer layer structure |
| 260 | |c 2014 | ||
| 270 | 1 | 0 | |m Litter, M.I.; Gerencia Química, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, 1650 San Martín, Prov. de Buenos Aires, Argentina; email: litter@cnea.gov.ar |
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| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a Nanoscale zerovalent iron (nZVI) particles were successfully employed for Cr(VI) removal from aqueous solutions at pH 3. It was found that the capacity of the system increases with increasing nZVI dosage. Starting at 300. μM, a complete Cr(VI) conversion was achieved in 30. min with a Fe:Cr(VI) molar ratio (MR) of 3, and 45% conversion with MR= 1 over the same period of time. The material exhibited an enhanced reactivity in comparison with other previously tested similar materials. The proposed mechanism involves an initial reduction of Cr(VI) to Cr(III) by reaction with Fe0 or Fe(II) on the particle surface or in solution (secondary pathway), followed by an arrest on Cr(VI) removal attributed to the passivation of the surface of the nanoparticles. Passivation was confirmed by Raman and X-ray photoelectron spectroscopies (XPS). Furthermore, XPS analysis demonstrated that Cr(III) is the only Cr species present in the external layer of the nanoparticles after the reaction. Raman analysis and XPS measurements performed after mild sputtering showed that nZVI exposed to Cr(VI) presented a structure, from outside to inside, of hydroxychromites→magnetite→Fe0. © 2014 Elsevier B.V. |l eng | |
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PICT projects 512-2006, 0463-2011 | ||
| 536 | |a Detalles de la financiación: This work was supported by Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT, Argentina) PICT projects 512-2006 and 0463-2011. A special mention to Eng. Jan Slunský from NANO IRON, s.r.o. Contributions by Martha Ortiz to the TXRF measurements and Adriana Domínguez for SEM images are gratefully acknowledged. Appendix A | ||
| 593 | |a Gerencia Química, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, 1650 San Martín, Prov. de Buenos Aires, Argentina | ||
| 593 | |a Consejo Nacional de Investigaciones Científicas y Técnicas, Av. Rivadavia 1917, 1033 Ciudad Autónoma de Buenos Aires, Argentina | ||
| 593 | |a Departamento de Química Inorgánica, Analítica y Química Física, FCEN, Universidad de Buenos Aires, Ciudad Universitaria Pabellón II, 1428 Ciudad Autónoma de Buenos Aires, Argentina | ||
| 593 | |a Gerencia de Investigación y Aplicaciones, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, 1650 San Martín, Prov. de Buenos Aires, Argentina | ||
| 593 | |a Escuela de Ciencia y Tecnología, Universidad de Gral. San Martín, Campus Miguelete, Martin de Irigoyen 3100, 1650 San Martin, Prov. de Buenos Aires, Argentina | ||
| 593 | |a Instituto Balseiro, Universidad Nacional de Cuyo, Av. Bustillo 9500, 8400 Bariloche, Prov. de Río Negro, Argentina | ||
| 593 | |a Centro Atómico Bariloche, Comisión Nacional de Energía Atómica, Av. Bustillo 9500, 8400 Bariloche, Prov. de Río Negro, Argentina | ||
| 593 | |a Instituto de Investigación e Ingeniería Ambiental, Universidad Nacional de Gral. San Martín, Peatonal Belgrano 3563, 1 piso, 1650 San Martín, Prov. de Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a HEXAVALENT CHROMIUM |
| 690 | 1 | 0 | |a NANOSCALE ZEROVALENT IRON |
| 690 | 1 | 0 | |a RAMAN SPECTROSCOPY |
| 690 | 1 | 0 | |a XPS ANALYSIS |
| 700 | 1 | |a Quici, N. | |
| 700 | 1 | |a Beatriz Halac, E. | |
| 700 | 1 | |a Leyva, Ana Gabriela | |
| 700 | 1 | |a Custo, G. | |
| 700 | 1 | |a Bengio, Silvina | |
| 700 | 1 | |a Zampieri, G. | |
| 700 | 1 | |a Litter, M.I. | |
| 773 | 0 | |d 2014 |g v. 244 |h pp. 569-575 |p Chem. Eng. J. |x 13858947 |w (AR-BaUEN)CENRE-4151 |t Chemical Engineering Journal | |
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