Tracing the Iron Nitrosyl Complex [Fe(2,2'-bipyridine)(CN)3(NO)]-
The previously reported complex [Ph4P][Fe(bpy)(CN)3(NO)] (bpy = 2,2'-bipyridine) was synthesised and characterised in detail using UV/Vis absorption and IR spectroscopy, cyclic voltammetry, and single-crystal XRD. Detailed spectroelectrochemical (UV/Vis, IR and EPR) insight adds perfectly to th...
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| Otros Autores: | , , , , , |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
Wiley-VCH Verlag
2015
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 03030caa a22004577a 4500 | ||
|---|---|---|---|
| 001 | PAPER-13635 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518204401.0 | ||
| 008 | 170725s2015 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84921519358 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a EJICF | ||
| 100 | 1 | |a Foi, A. | |
| 245 | 1 | 0 | |a Tracing the Iron Nitrosyl Complex [Fe(2,2'-bipyridine)(CN)3(NO)]- |
| 260 | |b Wiley-VCH Verlag |c 2015 | ||
| 270 | 1 | 0 | |m Klein, A. |
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a The previously reported complex [Ph4P][Fe(bpy)(CN)3(NO)] (bpy = 2,2'-bipyridine) was synthesised and characterised in detail using UV/Vis absorption and IR spectroscopy, cyclic voltammetry, and single-crystal XRD. Detailed spectroelectrochemical (UV/Vis, IR and EPR) insight adds perfectly to the previous electrochemical characterisation of this complex. The description of this {Fe(NO)}7 complex as a low-spin FeII-NO· system based on the spectroscopic results is supported by DFT calculations. Reversible oxidation leads to the corresponding {Fe(NO)}6 (FeII-NO+) complex, whereas the reduction to the formal {Fe(NO)}8 species [presumably (FeII-NO-)] occurs irreversibly. When trying to synthesise further derivatives that contain other α-diimine ligands, only for the 1,10-phenanthroline (phen) derivative were some results obtained. For other ligands the obtained materials were too reactive. The reasons for such behaviour are also discussed. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |l eng | |
| 536 | |a Article in Press | ||
| 593 | |a Departamento de Química Inorgánica, Analítica, y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, INQUIMAE-CONICET, Ciudad Universitaria, Pabellón 2, Piso 3, C1428EHA Buenos Aires, Argentina | ||
| 593 | |a University of Chittagong, Chittagong 4331, Bangladesh | ||
| 593 | |a Universität zu Köln, Institut für Anorganische Chemie, Greinstraße 6, 50939 Köln | ||
| 690 | 1 | 0 | |a DI-IMINES |
| 690 | 1 | 0 | |a ELECTROCHEMISTRY |
| 690 | 1 | 0 | |a IR SPECTROSCOPY |
| 690 | 1 | 0 | |a IRON |
| 690 | 1 | 0 | |a NITROGEN OXIDES |
| 700 | 1 | |a Di Salvo, F. | |
| 700 | 1 | |a Doctorovich, F. | |
| 700 | 1 | |a Roy, T.G. | |
| 700 | 1 | |a Stirnat, K. | |
| 700 | 1 | |a Biewer, C. | |
| 700 | 1 | |a Klein, A. | |
| 773 | 0 | |d Wiley-VCH Verlag, 2015 |x 14341948 |w (AR-BaUEN)CENRE-1604 |t Eur. J. Inorg. Chem. | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-84921519358&doi=10.1002%2fejic.201403145&partnerID=40&md5=6aaeab917e96796183646a7767f05e57 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1002/ejic.201403145 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_14341948_v_n_p_Foi |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14341948_v_n_p_Foi |y Registro en la Biblioteca Digital |
| 961 | |a paper_14341948_v_n_p_Foi |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 74588 | ||