Diffusion-viscosity decoupling in supercooled glycerol aqueous solutions
The diffusion of ferrocene methanol in supercooled glycerol-water mixtures has been measured over a wide viscosity range, which allowed analyzing the composition dependence of the Stokes-Einstein breakdown (diffusion-viscosity decoupling). The observed decoupling exhibits a common behavior for all s...
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American Chemical Society
2015
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 10401caa a22009617a 4500 | ||
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| 001 | PAPER-13583 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518204358.0 | ||
| 008 | 190411s2015 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84920733849 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a JPCBF | ||
| 100 | 1 | |a Trejo González, J.A. | |
| 245 | 1 | 0 | |a Diffusion-viscosity decoupling in supercooled glycerol aqueous solutions |
| 260 | |b American Chemical Society |c 2015 | ||
| 270 | 1 | 0 | |m Corti, H.R.; Instituto de Quimica Fisica de Los Materiales, Medio Ambiente Y Energia (INQUIMAE-CONICET), Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos AiresArgentina |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a The diffusion of ferrocene methanol in supercooled glycerol-water mixtures has been measured over a wide viscosity range, which allowed analyzing the composition dependence of the Stokes-Einstein breakdown (diffusion-viscosity decoupling). The observed decoupling exhibits a common behavior for all studied compositions (glycerol mass fractions between 0.7 and 0.9), determined by the reduced temperature (T/Tg) of the mixtures. This result differs from that reported previously for the diffusion of glycerol in its aqueous solutions, where the reduced temperature for the decoupling decreases with increasing water content. We conclude that the contradictory results are only apparent, and they can be explained by the use of inconsistent extrapolated values of the viscosity of the glycerol-water mixtures in the supercooled region. (Figure Presented). © 2014 American Chemical Society. |l eng | |
| 593 | |a Instituto de Quimica Fisica de Los Materiales, Medio Ambiente Y Energia (INQUIMAE-CONICET), Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, Buenos Aires, 1428, Argentina | ||
| 593 | |a Departamento de Física de la Materia Condensada, Comisión Nacional de Energía Atómica, Av. General Paz 1499, San Martín, Buenos Aires, 1650, Argentina | ||
| 690 | 1 | 0 | |a DIFFUSION |
| 690 | 1 | 0 | |a MIXTURES |
| 690 | 1 | 0 | |a ORGANOMETALLICS |
| 690 | 1 | 0 | |a SOLUTIONS |
| 690 | 1 | 0 | |a SUPERCOOLING |
| 690 | 1 | 0 | |a VISCOSITY |
| 690 | 1 | 0 | |a COMPOSITION DEPENDENCE |
| 690 | 1 | 0 | |a FERROCENES |
| 690 | 1 | 0 | |a GLYCEROL-WATER MIXTURES |
| 690 | 1 | 0 | |a MASS FRACTION |
| 690 | 1 | 0 | |a SUPERCOOLED REGIONS |
| 690 | 1 | 0 | |a GLYCEROL |
| 700 | 1 | |a Longinotti, M.P. | |
| 700 | 1 | |a Corti, H.R. | |
| 773 | 0 | |d American Chemical Society, 2015 |g v. 119 |h pp. 257-262 |k n. 1 |p J Phys Chem B |x 15206106 |w (AR-BaUEN)CENRE-5879 |t Journal of Physical Chemistry B | |
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| 856 | 4 | 0 | |u https://doi.org/10.1021/jp509055v |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_15206106_v119_n1_p257_TrejoGonzalez |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15206106_v119_n1_p257_TrejoGonzalez |y Registro en la Biblioteca Digital |
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