SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling
The dielectric properties of elastomer composites formed by dispersions of bismuth ferrite (BiFeO3) multiferroic filler particles in styrene-butadiene rubber (SBR) were studied. The SBR/BiFeO3 films (10-100 μm) were prepared in the presence of electric (E) or magnetic fields (H), showing remarkable...
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American Chemical Society
2015
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| LEADER | 16147caa a22012497a 4500 | ||
|---|---|---|---|
| 001 | PAPER-13190 | ||
| 003 | AR-BaUEN | ||
| 005 | 20250519101139.0 | ||
| 008 | 190411s2015 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84944404645 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Saleh Medina, L.M. | |
| 245 | 1 | 0 | |a SBR/BiFeO3 Elastomer Capacitor Films Prepared under Magnetic and Electric Fields Displaying Magnetoelectric Coupling |
| 260 | |b American Chemical Society |c 2015 | ||
| 270 | 1 | 0 | |m Negri, R.M.; Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos AiresArgentina |
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| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a The dielectric properties of elastomer composites formed by dispersions of bismuth ferrite (BiFeO3) multiferroic filler particles in styrene-butadiene rubber (SBR) were studied. The SBR/BiFeO3 films (10-100 μm) were prepared in the presence of electric (E) or magnetic fields (H), showing remarkable characteristics in comparison with systems obtained in its absence. The dispersed multiferroic fillers form clusters of much smaller size when prepared under E or H. The dielectric constant, ε (measured up to 1 MHz), increases with BiFeO3 concentration until reaching saturation. The rise of ε was obtained at concentrations much lower for samples prepared in the presence of E or H than in its absence. Saturation is assigned to connectivity between filler clusters at the largest concentrations, increasing leakage currents and limiting the dielectric behavior. The whole dependence of ε with BiFeO3 concentration was described using a proposed model. The dc resistivities, ρ, increase with BiFeO3 concentration but remain high (ρ ≈ 10 Gω·cm), allowing using the films as capacitors with filter action between 100 kHz and 7 MHz. The films prepared in the presence of H present strong dependence of the ferroelectric response with magnetic fields applied after preparation; that is, electromagnetic coupling was observed in those samples. © 2015 American Chemical Society. |l eng | |
| 593 | |a Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina | ||
| 593 | |a Centro de Investigación en Hidratos de Carbono (CIHIDECAR, CONICET-UBA), Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina | ||
| 593 | |a Instituto de Ciencias, Universidad Nacional de General Sarmiento, Buenos Aires, Argentina | ||
| 593 | |a Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía, Atómica, Argentina | ||
| 593 | |a Escuela de Ciencia y Tecnología, Universidad Nacional de San Martín, Campus Miguelete, San Martín, Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a CAPACITORS |
| 690 | 1 | 0 | |a DIELECTRIC PROPERTIES |
| 690 | 1 | 0 | |a DIELECTRIC PROPERTIES OF SOLIDS |
| 690 | 1 | 0 | |a ELASTOMERS |
| 690 | 1 | 0 | |a ELECTRIC FIELDS |
| 690 | 1 | 0 | |a ELECTROMAGNETIC COUPLING |
| 690 | 1 | 0 | |a FERROELECTRIC FILMS |
| 690 | 1 | 0 | |a FILLERS |
| 690 | 1 | 0 | |a LEAKAGE CURRENTS |
| 690 | 1 | 0 | |a MAGNETIC FIELDS |
| 690 | 1 | 0 | |a MAGNETISM |
| 690 | 1 | 0 | |a RUBBER |
| 690 | 1 | 0 | |a STYRENE |
| 690 | 1 | 0 | |a BISMUTH FERRITES |
| 690 | 1 | 0 | |a DIELECTRIC BEHAVIOR |
| 690 | 1 | 0 | |a ELASTOMER COMPOSITES |
| 690 | 1 | 0 | |a FERROELECTRIC RESPONSE |
| 690 | 1 | 0 | |a MAGNETIC AND ELECTRIC FIELDS |
| 690 | 1 | 0 | |a MAGNETOELECTRIC COUPLINGS |
| 690 | 1 | 0 | |a STRONG DEPENDENCES |
| 690 | 1 | 0 | |a STYRENE BUTADIENE RUBBER |
| 690 | 1 | 0 | |a FILM PREPARATION |
| 700 | 1 | |a Jorge, Guillermo Antonio | |
| 700 | 1 | |a Rubi, D. | |
| 700 | 1 | |a D'Accorso, N. | |
| 700 | 1 | |a Negri, R.M. | |
| 773 | 0 | |d American Chemical Society, 2015 |g v. 119 |h pp. 23319-23328 |k n. 41 |p J. Phys. Chem. C |x 19327447 |t Journal of Physical Chemistry C | |
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| 856 | 4 | 0 | |u https://doi.org/10.1021/acs.jpcc.5b06056 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_19327447_v119_n41_p23319_SalehMedina |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_19327447_v119_n41_p23319_SalehMedina |y Registro en la Biblioteca Digital |
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