Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
1980
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 03593caa a22004577a 4500 | ||
|---|---|---|---|
| 001 | PAPER-1310 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203039.0 | ||
| 008 | 190411s1980 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-49149144546 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a TELEA | ||
| 100 | 1 | |a Nudelman, N.S. | |
| 245 | 1 | 0 | |a Unusual dealkylations and rearrangements in aromatic nucleophilic substitution |
| 260 | |c 1980 | ||
| 270 | 1 | 0 | |m Nudelman, N.S.; Depto de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon II, 1428 Buenos Aires, Argentina |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Nudelman, ortho Effects on Nucleophilic Aromatic Substitution. The Reactions of 6-R-2-Nitrochlorobenzenes with Piperidine in Benzene (1965) The Journal of Organic Chemistry, 30, p. 3365 | ||
| 504 | |a Nudelman, (1978) Anales Asoc. Quím. Arg., 66, p. 89 | ||
| 504 | |a Kolthoff, Guss, (1938) J. Am. Chem. Soc., 60, p. 2516 | ||
| 504 | |a Bunnett, Nudelman, (1969) J. Org. Chem., 34, p. 2043 | ||
| 504 | |a Ainsworth, Easton, Thermal Elimination Reaction of Aliphatic Amine Salts (1962) The Journal of Organic Chemistry, 24, p. 4118 | ||
| 504 | |a Schölkopf, Recent Results in Carbanion Chemistry (1970) Angewandte Chemie International Edition in English, 9, p. 763. , Int. Ed. Engl | ||
| 504 | |a Nudelman, Garrido, (1976) J. Chem. Soc., p. 1256. , Perkin Trans. II | ||
| 504 | |a Benzene was kept over sodium strings several days and twice distilled over sodium (water content≤0.02% by Karl-Fisher method); Nudelman, Brieux, (1970) Anales Asoc. Quím. Arg., 58, p. 217 | ||
| 504 | |a Bunnett, Kato, Nudelman, (1969) J. Org. Chem., 34, p. 785 | ||
| 504 | |a Nudelman, Brieux, (1970) Anales Asoc. Quím. Arg., 58, p. 217 | ||
| 504 | |a Bernasconi, (1973) MTP Int. Rev. Sci., Org. Chem., 3, p. 33. , Ser. One | ||
| 520 | 3 | |a The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and dicyclohexylamine. A carbanionic mechanism is proposed. © 1980. |l eng | |
| 536 | |a Detalles de la financiación: CientSficaa y TE?cnicas (bgentina) ACKNOWLEDCMF and from the Organization of the AmericanS tates is grate-ESN: Financial support from the Cbnsejo National de Investigaciones fully acknowledged. | ||
| 593 | |a Depto de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon II, 1428 Buenos Aires, Argentina | ||
| 700 | 1 | |a Socolovsky, S.E. | |
| 773 | 0 | |d 1980 |g v. 21 |h pp. 3331-3334 |k n. 35 |p Tetrahedron Lett. |x 00404039 |w (AR-BaUEN)CENRE-415 |t Tetrahedron Letters | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-49149144546&doi=10.1016%2fS0040-4039%2800%2978681-3&partnerID=40&md5=fdd972c276840aa73eee720199cc29b5 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1016/S0040-4039(00)78681-3 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00404039_v21_n35_p3331_Nudelman |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v21_n35_p3331_Nudelman |y Registro en la Biblioteca Digital |
| 961 | |a paper_00404039_v21_n35_p3331_Nudelman |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 963 | |a VARI | ||
| 999 | |c 62263 | ||