Thermochemical conversion of coal from rio turbio minefield with a sustainable energy plantation: On kinetics of co-pyrolysis

Kinetics of co-pyrolysis of blends composed of equal proportions of the subbituminous coal from the Río Turbio minefield and stems from giant reed (Arundo donax L.), as representative biomass from sustainable energy plantations, is characterized accounting for the individual pyrolytic behavior and m...

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Autor principal: Bonelli, P.R
Otros Autores: Zilli, D.A, González, J.D, Buonomo, E.L, Cukierman, A.L
Formato: Acta de conferencia Capítulo de libro
Lenguaje:Inglés
Publicado: Asociacion Argentina de Ingenieros Quimicos, Ciudad Autonoma de Buenos Aires, Argentina 2006
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
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100 1 |a Bonelli, P.R. 
245 1 0 |a Thermochemical conversion of coal from rio turbio minefield with a sustainable energy plantation: On kinetics of co-pyrolysis 
260 |b Asociacion Argentina de Ingenieros Quimicos, Ciudad Autonoma de Buenos Aires, Argentina  |c 2006 
270 1 0 |m Cukierman, A.L.; Programa de Investigacion y Desarrollo de Fuentes Alternativas de Materias Primas y Energia-PINMATE, Depto. de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2620, Ciudad Universitaria, Argentina; email: analea@di.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
504 |a Balci, S., Dogu, T., Yücel, H., Pyrolysis kinetics of lignocellulosic materials (1993) Ind. Eng. Chem. Res., 32, p. 2573 
504 |a Basso, M.C., Cukierman, A.L., Arundo donax-based activated carbons for aqueous-phase adsorption of volatile organic compounds (2005) Ind. Eng. Chem. Res., 44, p. 2091 
504 |a Basso, M.C., Cerrella, E.G., Buonomo, E.L., Bonelli, P.R., Cukierman, A.L., Thermochemical conversion of arundo donax into useful solid products (2005) Energy Sources, 27 (15), p. 1429 
504 |a Biagini, E., Lippi, F., Petraca, L., Tognotti, L., Devolatilization rate of biomasses and coal-biomass blends: An experimental investigation (2002) Fuel, 81 (8), p. 1041 
504 |a Bonelli, P., Della Rocca, P., Cerrella, E., Cukierman, A., Effect of pyrolysis temperature on composition, surface properties and thermal degradation rates of Brazil nut shells (2001) Bioresource Technology, 76, p. 15 
504 |a Bonelli, P.R., Buonomo, E.L., Cukierman, A.L., On pyrolysis and co-pyrolysis of sugarcane bagasse with an argentinean subbituminous coal (2006) Energy Sources, , in press 
504 |a Bridgewater, A., Biomass for energy (2006) J. of the Science of Food and Agriculture, 86, p. 1755 
504 |a Burnham, A.K., Braun, R.L., Global kinetics analysis of complex materials (1999) Energy and Fuels, 13, p. 1 
504 |a Channiwala, S., Parikh, P., A unified correlation for HHV of solid, liquid and gaseous fuels (2002) Fuel, 81, p. 1051 
504 |a Collot, A., Zhuo, Y., Dugwell, D., Kandiyoti, R., Co-pyrolysis and co-gasification of coal and biomass in bench-scale fixed-bed and fluidised bed reactors (1999) Fuel, 78, p. 667 
504 |a Cordero, T., Rodríguez-Mirsol, J., Pastrana, J., Rodríguez, J., Improved solid fuels from co-pyrolysis of high sulphur content coal and different lignocellulosic wastes (2004) Fuel, 83, p. 1585 
504 |a Demirbas, A., Bioenergy, global warming, and environmental impacts (2004) Energy Sources, 26, p. 225 
504 |a Kastanaki, E., Vamvuka, D., Grammelis, P., Kakaras, E., Thermogravimetric studies of the behavior of lignite-biomass blends during devolatilization (2002) Fuel Processing Technology, 77-78, p. 159 
504 |a Lewandowski, I., Scurlock, J.M.O., Lindvall, E., Christou, M., The development and current status of perennial rhizomatous grasses as energy crops in the US and Europe (2003) Biomass and Bioenergy, 25, p. 335 
504 |a Mesri, C., Moghtaderi, B., Lack of synergetic effects in the pyrolytic characteristics of woody biomass / coal blends under low and high heating rate regimes (2002) Biomass & Bioenergy, 23, p. 55 
504 |a Ochoa, J., Bonelli, P., Cassanello, M., Cukierman, A.L., Thermal conversion processes of low-rank coals from argentinean minefields (2000) Trends in Chem. Eng., 6, p. 43 
504 |a Pascoal Neto, C., Seca, A., Nunes, A.M., Variations in chemical composition and structure of macromolecular components in different morphological regions and maturity stages of arundo donax (1997) Industrial Crops and Products, 6, p. 51 
504 |a Ulloa, C., Gordon, A., García, X., Distribution of activation energy model applied to the rapid pyrolysis of coal blends (2004) J. Anal. Appl. Pyrolysis, 71, p. 465 
504 |a Vuthaluru, H., Thermal behaviour of coal/Biomass blends during co-pyrolysis (2003) Fuel Processing Technology, 85, p. 141 
504 |a Vuthaluru, H., Investigations into pyrolytic behaviour of coal/Biomass blends using thermogravimetric analysis (2004) Bioresource Technology, 92, p. 187 
504 |a (2006), http://www.wci.coal.comA4 - Atanor; Compania Mega S.A.; Consejo Federal de Inversiones (CFI); Dow; et al.; Petroquimica Rio Tercero SA (PRIII) 
520 3 |a Kinetics of co-pyrolysis of blends composed of equal proportions of the subbituminous coal from the Río Turbio minefield and stems from giant reed (Arundo donax L.), as representative biomass from sustainable energy plantations, is characterized accounting for the individual pyrolytic behavior and main physicochemical properties of both fuels. Non-isothermal thermogravimetric measurements for the blend and individual constituents, from ambient temperature up to 900 °C under flowing nitrogen, and data modeling are performed. Coal pyrolysis begins at a higher temperature (∼275 °C) and proceeds more gradually than the biomass, whereas the blend exhibits an intermediate pyrolytic behavior between those of the constituent fuels. A model which assumes variations in the activation energy with process evolution, through an increasing dependence on temperature and solid conversion, provides a suitable description of pyrolysis and co-pyrolysis results over the entire temperature range. The higher content of volatile matter of the biomass and differences in chemical structure between coal and biomass explain the pyrolytic behavior ascertained for the individual fuels and the blend. They are reflected in the estimated kinetic parameters.  |l eng 
593 |a Programa de Investigacion y Desarrollo de Fuentes Alternativas de Materias Primas y Energia-PINMATE, Depto. de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2620, Ciudad Universitaria, Buenos Aires, C1428BGA, Argentina 
690 1 0 |a ARGENTINEAN SUBBITUMINOUS COAL 
690 1 0 |a CO-PYROLYSIS 
690 1 0 |a ENERGY CROP BIOMASS BLEND 
690 1 0 |a KINETIC CHARACTERIZATION 
690 1 0 |a ACTIVATION ENERGY 
690 1 0 |a BIOMASS 
690 1 0 |a BLENDING 
690 1 0 |a COAL 
690 1 0 |a CROPS 
690 1 0 |a ENERGY CONSERVATION 
690 1 0 |a FUELS 
690 1 0 |a KINETICS 
690 1 0 |a COPYROLYSIS 
690 1 0 |a ENERGY CROPS 
690 1 0 |a KINETIC CHARACTERIZATION 
690 1 0 |a PHYSICOCHEMICAL PROPERTY 
690 1 0 |a SUBBITUMINOUS COAL 
690 1 0 |a SUSTAINABLE ENERGY 
690 1 0 |a THERMOCHEMICAL CONVERSION 
690 1 0 |a THERMOGRAVIMETRIC MEASUREMENT 
690 1 0 |a PYROLYSIS 
700 1 |a Zilli, D.A. 
700 1 |a González, J.D. 
700 1 |a Buonomo, E.L. 
700 1 |a Cukierman, A.L. 
711 2 |d 1 October 2006 through 4 October 2006  |g Código de la conferencia: 123803 
773 0 |d Asociacion Argentina de Ingenieros Quimicos, Ciudad Autonoma de Buenos Aires, Argentina, 2006  |p Interam. Congr. Chem. Eng., CIIQ Argent. Congr. Chem. Eng., CAIQ. - Innov. Manag. Sustain. Dev.  |n XXII Interamerican Congress of Chemical Engineering, CIIQ 2006 and V Argentinian Congress of Chemical Engineering, CAIQ 2006 - Innovation and Management for Sustainable Development  |t 22nd Interamerican Congress of Chemical Engineering, CIIQ 2006 and 5th Argentinian Congress of Chemical Engineering, CAIQ 2006 
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