Alkaloids of Datura ferox from Argentina
Chromatographic procedures (HPLC, GC-MS) are outlined in this paper for the analysis of alkaloids in poisonous Datura ferox seeds of Argentina, from which previously only quantitative analysis for scopolamine was known. Five additional tropane alkaloids are now identified as 3α-tigloyloxytropane (ti...
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1995
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| LEADER | 13904caa a22015497a 4500 | ||
|---|---|---|---|
| 001 | PAPER-12434 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518204238.0 | ||
| 008 | 190411s1995 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0029623084 | |
| 024 | 7 | |2 cas |a hyoscyamine, 101-31-5, 306-03-6; nicotine, 54-11-5; scopolamine, 138-12-5, 51-34-3, 55-16-3; Alkaloids; Plant Extracts | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a JOETD | ||
| 100 | 1 | |a Vitale, A.A. | |
| 245 | 1 | 0 | |a Alkaloids of Datura ferox from Argentina |
| 260 | |c 1995 | ||
| 270 | 1 | 0 | |m Pomilio, A.B.; PROPLAME-CONICET, Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Pabellon 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a Chromatographic procedures (HPLC, GC-MS) are outlined in this paper for the analysis of alkaloids in poisonous Datura ferox seeds of Argentina, from which previously only quantitative analysis for scopolamine was known. Five additional tropane alkaloids are now identified as 3α-tigloyloxytropane (tigloyltropeine), 3-phenylacetoxy-6β,7β-epoxytropane (3-phenylacetoxyscopine), aposcopolamine (apohyoscine), 7β-hydroxy-6β-propenyloxy-3α-tropoyloxytropane, traces of 7β-hydroxy-6β-isovaleroyloxy-3α-tigloyloxytropane and a pyrrolidine alkaloid, hygrine. Two new structures, 3-phenylacetoxy-6β,7β-epoxytropane (3-phenylacetoxyscopine) and 7β-hydroxy-6β-propenyloxy-3α-tropoyloxytropane, are proposed on the basis of their spectra. Hyoscyamine, nicotine and tropane N-oxides were not detected in all samples studied. © 1995. |l eng | |
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: Thanks are due to CONICET (Argentina) and Universidad de Buenos Aires (UBA) for financial support; to UMYMFOR-CONICET for GC-MS facilities; to Ing. Agr. Marcel0 J. Schang (INTA-EEA Pergamino, Argentina) for collecting the seeds; to Dr. Enrique M. Zallocchi (UBA) for identification of the plant material and to Mr. Jorge Asnarez for technical assistance in running GC-MS. One of us (A. A.) also thanks UBA for a research fellowship. | ||
| 593 | |a PROPLAME-CONICET, Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Pabellon 2, Ciudad Universitaria, 1428 Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a 3-PHENYLACETOXY-6Β,7Β-EPOXYTROPANE (3-PHENYLACETOXYSCOPINE) |
| 690 | 1 | 0 | |a 3Α-TIGLOYLOXYTROPANE (TIGLOYLTROPEINE) |
| 690 | 1 | 0 | |a 7Β-HYDROXY-6Β-ISOVALEROYLOXY-3Α-TIGLOYLOXYTROPANE |
| 690 | 1 | 0 | |a 7Β-HYDROXY-6Β-PROPENYLOXY-3Α-TROPOYLOXYTROPANE |
| 690 | 1 | 0 | |a APOSCOPOLAMINE (APOHYOSCINE) |
| 690 | 1 | 0 | |a DATURA FEROX |
| 690 | 1 | 0 | |a GC-MS |
| 690 | 1 | 0 | |a HPLC |
| 690 | 1 | 0 | |a HYGRINE |
| 690 | 1 | 0 | |a SCOPOLAMINE (HYOSCINE) |
| 690 | 1 | 0 | |a TROPANE ALKALOIDS |
| 690 | 1 | 0 | |a HYOSCYAMINE |
| 690 | 1 | 0 | |a NICOTINE |
| 690 | 1 | 0 | |a PLANT EXTRACT |
| 690 | 1 | 0 | |a SCOPOLAMINE |
| 690 | 1 | 0 | |a TROPANE ALKALOID |
| 690 | 1 | 0 | |a TROPANE DERIVATIVE |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a DRUG DETERMINATION |
| 690 | 1 | 0 | |a DRUG ISOLATION |
| 690 | 1 | 0 | |a DRUG STRUCTURE |
| 690 | 1 | 0 | |a DRUG TOXICITY |
| 690 | 1 | 0 | |a GAS CHROMATOGRAPHY |
| 690 | 1 | 0 | |a HIGH PERFORMANCE LIQUID CHROMATOGRAPHY |
| 690 | 1 | 0 | |a MASS SPECTROMETRY |
| 690 | 1 | 0 | |a NONHUMAN |
| 690 | 1 | 0 | |a PLANT SEED |
| 690 | 1 | 0 | |a ALKALOIDS |
| 690 | 1 | 0 | |a CHROMATOGRAPHY, HIGH PRESSURE LIQUID |
| 690 | 1 | 0 | |a HUMANS |
| 690 | 1 | 0 | |a PLANT EXTRACTS |
| 690 | 1 | 0 | |a SEEDS |
| 651 | 4 | |a ARGENTINA | |
| 651 | 4 | |a ARGENTINA | |
| 700 | 1 | |a Acher, A. | |
| 700 | 1 | |a Pomilio, A.B. | |
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