XPS and Electrochemical Studies of Chromium Modified Passive Iron Electrodes
The modification of passive iron electrodes by chromate ion has been studied in three different electrochemical experiments: potentiostatic passivation, open-circuit passivation, and cyclic potential treatment. XPS surface composition and composition-depth profiles obtained by argon ion-sputtering o...
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1988
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 06541caa a22007937a 4500 | ||
|---|---|---|---|
| 001 | PAPER-12042 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518204215.0 | ||
| 008 | 190411s1988 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0023965304 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Calve, E.J. | |
| 245 | 1 | 0 | |a XPS and Electrochemical Studies of Chromium Modified Passive Iron Electrodes |
| 260 | |c 1988 | ||
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Lumsden, J.B., Staehle, R.W., (1972) Scr. Metall., 6, p. 1205 | ||
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| 504 | |a Olefjord, I., Elfstrom, B.O., (1982) Corrosion, 38, p. 46. , Houston | ||
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| 504 | |a Asami, K., Hashimoto, K., Shimodara, S., (1976) Corros. Sci., 16, p. 387 | ||
| 504 | |a Asami, K., Hashimoto, H., (1977) Corros. Sci., 17, p. 559 | ||
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| 504 | |a Pallotta, C.D., Gonnet, R., Calvo, E.J., J. Eiectroanal. Chem., , Accepted for publication | ||
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| 504 | |a Carlson, T.A., (1975) Photoelectron and Auger Spectroscopy, , Plenum Press, New York | ||
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| 504 | |a le Goff, H., Pallotta, C.D., preparation; Long, G.G., Kruger, J., Black, D.R., Kuriyama, M., (1983) Journal of the Electrochemical Society, 130, p. 240 | ||
| 504 | |a O'Grady, W.E., (1987) Journal of the Electrochemical Society, 127, p. 555 | ||
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| 520 | 3 | |a The modification of passive iron electrodes by chromate ion has been studied in three different electrochemical experiments: potentiostatic passivation, open-circuit passivation, and cyclic potential treatment. XPS surface composition and composition-depth profiles obtained by argon ion-sputtering of the modified electrodes show different patterns depending on the electrochemical treatment. Two electrokinetic pathways for the reduction of chromate associated with the different chromium concentration profiles in the film are also apparent and have been related to the reductive precipitation of hydrous Cr(III) species, and to the chromium redox centers entrapped in the passive layer. The latter permanent modification of the passive layer is only obtained by repetitive oxidation-reduction cycles of iron in alkaline chromate and has similarities with passive layers on Fe-Cr alloys. © 1988, The Electrochemical Society, Inc. All rights reserved. |l eng | |
| 593 | |a Permanent Research Staff of the Argentine Science & Technology Research Council, Sector Electroquimica Apticada, Instituto Nacional de Tecnologia Industrial, c.c. 157, San Martin, 1650 Buenos Aires, Argentina | ||
| 593 | |a Departamento de Quimica Inorganica, Analitica y Fisicoquimica, Facultad de Ciencias Exactas y Naturales, UBA, Ciudad Universitaria, Pab II, 1428, Buenos Aires, Argentina | ||
| 593 | |a Departamento de Materiales, Gerencia de Desarrollo, Comision Nacional de Energia Atomica, .Avenida Libertador 8250, 1429, Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a CHEMICAL REACTIONS - REDOX |
| 690 | 1 | 0 | |a CHROMIUM AND ALLOYS |
| 690 | 1 | 0 | |a IRON AND ALLOYS - SURFACES |
| 690 | 1 | 0 | |a SPECTROSCOPY, ELECTRON - APPLICATIONS |
| 690 | 1 | 0 | |a SURFACES - SPECTROSCOPIC ANALYSIS |
| 690 | 1 | 0 | |a CHROMATE |
| 690 | 1 | 0 | |a CONCENTRATION DEPTH PROFILES |
| 690 | 1 | 0 | |a ELECTROKINETIC PATHWAYS |
| 690 | 1 | 0 | |a PASSIVATING LAYERS |
| 690 | 1 | 0 | |a ELECTRODES |
| 700 | 1 | |a Pallotta, C.D. | |
| 773 | 0 | |d 1988 |g v. 135 |h pp. 314-320 |k n. 2 |p J Electrochem Soc |x 00134651 |w (AR-BaUEN)CENRE-38 |t Journal of the Electrochemical Society | |
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| 856 | 4 | 0 | |u https://doi.org/10.1149/1.2095607 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00134651_v135_n2_p314_Calve |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134651_v135_n2_p314_Calve |y Registro en la Biblioteca Digital |
| 961 | |a paper_00134651_v135_n2_p314_Calve |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 72995 | ||