Structural and magnetic properties of Fe2-xCoSm xO4 - Nanoparticles and Fe2-xCoSm xO4 - PDMS magnetoelastomers as a function of Sm content

We have synthesized magnetic Fe2-xCoSmxO4 nanoparticles (NPs) by means of the coprecipitation method, varying Sm content from x=0 to x=0.5. Energy-dispersive X-ray spectroscopy showed agreement between the metal proportion of the obtained nanoparticles and the stoichiometric mixture of cations used...

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Autor principal: Ruiz, M.M
Otros Autores: Mietta, J.L, Soledad Antonel, P., Pérez, O.E, Martín Negri, R., Jorge, Guillermo Antonio
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2013
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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024 7 |2 scopus  |a 2-s2.0-84869161731 
030 |a JMMMD 
040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
100 1 |a Ruiz, M.M. 
245 1 0 |a Structural and magnetic properties of Fe2-xCoSm xO4 - Nanoparticles and Fe2-xCoSm xO4 - PDMS magnetoelastomers as a function of Sm content 
260 |c 2013 
270 1 0 |m Jorge, G.; Departamento de Física, UBA, Pabellón I (C1428EGA), Buenos Aires, Argentina; email: gjorge@df.uba.ar 
504 |a Johannsen, M., Gneveckow, U., Thiesen, B., Taymoorian, K., Cho, C.H., Waldöfner, N., Scholz, R., Wust, P., (2007) European Urology, 52, p. 1653 
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504 |a Soledad Antonel, P., Jorge, G., Perez, O.E., Butera, A., Gabriela Leyva, A., Negri, R.M., (2011) Journal of Applied Physics, 110 
504 |a Mietta, J.L., Ruiz, M.M., Antonel, P.S., Perez, O.E., Butera, A., Jorge, G., Negri, R.M., (2012) Langmuir, 28, p. 6985 
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506 |2 openaire  |e Política editorial 
520 3 |a We have synthesized magnetic Fe2-xCoSmxO4 nanoparticles (NPs) by means of the coprecipitation method, varying Sm content from x=0 to x=0.5. Energy-dispersive X-ray spectroscopy showed agreement between the metal proportion of the obtained nanoparticles and the stoichiometric mixture of cations used for the synthesis. Part of the particles were heated at 800 °C, and both were characterized by X-ray diffraction, scanning electron microscope imaging and magnetization measurements. Physical and magnetic properties were analyzed as a function of Sm content, before and after the heating treatment. A phase segregation is found for the calcined nanoparticles with large Sm content. The magnetic remanence, saturation and coercive field were investigated as a function of Sm content for both heated and unheated (as-prepared) particles. Polydimethylsiloxane-NPs magnetoelastomers were prepared and cured under an external uniform magnetic field, obtaining structured anisotropic composites, in which inorganic needles (columnar micrometric structures) oriented in the direction of the magnetic field are formed. Young modulus and remanent magnetic moment were measured and magnetization time relaxation experiments were performed in the directions parallel and perpendicular to the needles in order to determine the magnetic and elastic anisotropy of the composites. The elastic modulus measured parallel to the needles resulted almost twice in magnitude with respect to the perpendicular modulus. The measured magnetic anisotropy of the composites is probably due to the enhanced interparticle interaction within a needle and the freezing of an preferred easy axis distribution among the particles at the curing process. © 2012 Elsevier B.V.  |l eng 
536 |a Detalles de la financiación: Phycological Society of America 
536 |a Detalles de la financiación: National Science and Technology Development Agency 
536 |a Detalles de la financiación: National Research Council of Science and Technology 
536 |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PICT 2011-0377 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas 
536 |a Detalles de la financiación: PSA, GJ and RMN are research members of the National Council of Research and Technology (CONICET, Argentina). MMR is a doctoral fellowship of CONICET. JLM received a fellowship of the University of Buenos Aires (UBA). Financial support was received from the National Agency for Promotion of Science and Technology ( ANPCYT , PICT 2011-0377 ). Appendix A 
593 |a Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Av. Cantilo s/n (1428), Buenos Aires, Argentina 
593 |a Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Av. Cantilo s/n (1428), Buenos Aires, Argentina 
593 |a Instituto de Física de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Av. Cantilo s/n (1428), Buenos Aires, Argentina 
593 |a Instituto de Ciencias, Universidad Nacional de General Sarmiento, J.M. Gutiérrez 1150 (1613), Los Polvorines, Buenos Aires, Argentina 
690 1 0 |a MAGNETIC COMPOSITES 
690 1 0 |a MAGNETIC NANOPARTICLES 
690 1 0 |a MAGNETOELASTOMERS 
690 1 0 |a MAGNETORHEOELASTOMERS 
690 1 0 |a ANISOTROPIC COMPOSITES 
690 1 0 |a COERCIVE FIELD 
690 1 0 |a COPRECIPITATION METHOD 
690 1 0 |a CURING PROCESS 
690 1 0 |a EASY AXIS 
690 1 0 |a ELASTIC ANISOTROPY 
690 1 0 |a ENERGY DISPERSIVE X-RAY SPECTROSCOPY 
690 1 0 |a HEATING TREATMENTS 
690 1 0 |a INTER-PARTICLE INTERACTION 
690 1 0 |a MAGNETIC COMPOSITES 
690 1 0 |a MAGNETIC NANOPARTICLES 
690 1 0 |a MAGNETIC REMANENCE 
690 1 0 |a MAGNETIZATION MEASUREMENTS 
690 1 0 |a MAGNETOELASTOMERS 
690 1 0 |a MAGNETORHEOELASTOMERS 
690 1 0 |a MICROMETRIC STRUCTURES 
690 1 0 |a PHASE SEGREGATIONS 
690 1 0 |a SCANNING ELECTRON MICROSCOPE 
690 1 0 |a STOICHIOMETRIC MIXTURES 
690 1 0 |a STRUCTURAL AND MAGNETIC PROPERTIES 
690 1 0 |a YOUNG MODULUS 
690 1 0 |a ASSOCIATION REACTIONS 
690 1 0 |a CALCINATION 
690 1 0 |a ENERGY DISPERSIVE SPECTROSCOPY 
690 1 0 |a MAGNETIC ANISOTROPY 
690 1 0 |a MAGNETIC FIELDS 
690 1 0 |a MAGNETIC MOMENTS 
690 1 0 |a MAGNETIZATION 
690 1 0 |a METAL NANOPARTICLES 
690 1 0 |a NEEDLES 
690 1 0 |a SCANNING ELECTRON MICROSCOPY 
690 1 0 |a SILICONES 
690 1 0 |a SYNTHESIS (CHEMICAL) 
690 1 0 |a X RAY DIFFRACTION 
690 1 0 |a NANOMAGNETICS 
700 1 |a Mietta, J.L. 
700 1 |a Soledad Antonel, P. 
700 1 |a Pérez, O.E. 
700 1 |a Martín Negri, R. 
700 1 |a Jorge, Guillermo Antonio 
773 0 |d 2013  |g v. 327  |h pp. 11-19  |p J Magn Magn Mater  |x 03048853  |w (AR-BaUEN)CENRE-5651  |t Journal of Magnetism and Magnetic Materials 
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856 4 0 |u https://doi.org/10.1016/j.jmmm.2012.09.020  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_03048853_v327_n_p11_Ruiz  |y Handle 
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