Structural and magnetic properties of Fe2-xCoSm xO4 - Nanoparticles and Fe2-xCoSm xO4 - PDMS magnetoelastomers as a function of Sm content
We have synthesized magnetic Fe2-xCoSmxO4 nanoparticles (NPs) by means of the coprecipitation method, varying Sm content from x=0 to x=0.5. Energy-dispersive X-ray spectroscopy showed agreement between the metal proportion of the obtained nanoparticles and the stoichiometric mixture of cations used...
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2013
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LEADER | 09918caa a22012617a 4500 | ||
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001 | PAPER-11786 | ||
003 | AR-BaUEN | ||
005 | 20250519101615.0 | ||
008 | 190411s2013 xx ||||fo|||| 00| 0 eng|d | ||
024 | 7 | |2 scopus |a 2-s2.0-84869161731 | |
030 | |a JMMMD | ||
040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
100 | 1 | |a Ruiz, M.M. | |
245 | 1 | 0 | |a Structural and magnetic properties of Fe2-xCoSm xO4 - Nanoparticles and Fe2-xCoSm xO4 - PDMS magnetoelastomers as a function of Sm content |
260 | |c 2013 | ||
270 | 1 | 0 | |m Jorge, G.; Departamento de Física, UBA, Pabellón I (C1428EGA), Buenos Aires, Argentina; email: gjorge@df.uba.ar |
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506 | |2 openaire |e Política editorial | ||
520 | 3 | |a We have synthesized magnetic Fe2-xCoSmxO4 nanoparticles (NPs) by means of the coprecipitation method, varying Sm content from x=0 to x=0.5. Energy-dispersive X-ray spectroscopy showed agreement between the metal proportion of the obtained nanoparticles and the stoichiometric mixture of cations used for the synthesis. Part of the particles were heated at 800 °C, and both were characterized by X-ray diffraction, scanning electron microscope imaging and magnetization measurements. Physical and magnetic properties were analyzed as a function of Sm content, before and after the heating treatment. A phase segregation is found for the calcined nanoparticles with large Sm content. The magnetic remanence, saturation and coercive field were investigated as a function of Sm content for both heated and unheated (as-prepared) particles. Polydimethylsiloxane-NPs magnetoelastomers were prepared and cured under an external uniform magnetic field, obtaining structured anisotropic composites, in which inorganic needles (columnar micrometric structures) oriented in the direction of the magnetic field are formed. Young modulus and remanent magnetic moment were measured and magnetization time relaxation experiments were performed in the directions parallel and perpendicular to the needles in order to determine the magnetic and elastic anisotropy of the composites. The elastic modulus measured parallel to the needles resulted almost twice in magnitude with respect to the perpendicular modulus. The measured magnetic anisotropy of the composites is probably due to the enhanced interparticle interaction within a needle and the freezing of an preferred easy axis distribution among the particles at the curing process. © 2012 Elsevier B.V. |l eng | |
536 | |a Detalles de la financiación: Phycological Society of America | ||
536 | |a Detalles de la financiación: National Science and Technology Development Agency | ||
536 | |a Detalles de la financiación: National Research Council of Science and Technology | ||
536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PICT 2011-0377 | ||
536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
536 | |a Detalles de la financiación: PSA, GJ and RMN are research members of the National Council of Research and Technology (CONICET, Argentina). MMR is a doctoral fellowship of CONICET. JLM received a fellowship of the University of Buenos Aires (UBA). Financial support was received from the National Agency for Promotion of Science and Technology ( ANPCYT , PICT 2011-0377 ). Appendix A | ||
593 | |a Instituto de Química Física de Materiales, Ambiente y Energía (INQUIMAE), Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Av. Cantilo s/n (1428), Buenos Aires, Argentina | ||
593 | |a Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Av. Cantilo s/n (1428), Buenos Aires, Argentina | ||
593 | |a Instituto de Física de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Av. Cantilo s/n (1428), Buenos Aires, Argentina | ||
593 | |a Instituto de Ciencias, Universidad Nacional de General Sarmiento, J.M. Gutiérrez 1150 (1613), Los Polvorines, Buenos Aires, Argentina | ||
690 | 1 | 0 | |a MAGNETIC COMPOSITES |
690 | 1 | 0 | |a MAGNETIC NANOPARTICLES |
690 | 1 | 0 | |a MAGNETOELASTOMERS |
690 | 1 | 0 | |a MAGNETORHEOELASTOMERS |
690 | 1 | 0 | |a ANISOTROPIC COMPOSITES |
690 | 1 | 0 | |a COERCIVE FIELD |
690 | 1 | 0 | |a COPRECIPITATION METHOD |
690 | 1 | 0 | |a CURING PROCESS |
690 | 1 | 0 | |a EASY AXIS |
690 | 1 | 0 | |a ELASTIC ANISOTROPY |
690 | 1 | 0 | |a ENERGY DISPERSIVE X-RAY SPECTROSCOPY |
690 | 1 | 0 | |a HEATING TREATMENTS |
690 | 1 | 0 | |a INTER-PARTICLE INTERACTION |
690 | 1 | 0 | |a MAGNETIC COMPOSITES |
690 | 1 | 0 | |a MAGNETIC NANOPARTICLES |
690 | 1 | 0 | |a MAGNETIC REMANENCE |
690 | 1 | 0 | |a MAGNETIZATION MEASUREMENTS |
690 | 1 | 0 | |a MAGNETOELASTOMERS |
690 | 1 | 0 | |a MAGNETORHEOELASTOMERS |
690 | 1 | 0 | |a MICROMETRIC STRUCTURES |
690 | 1 | 0 | |a PHASE SEGREGATIONS |
690 | 1 | 0 | |a SCANNING ELECTRON MICROSCOPE |
690 | 1 | 0 | |a STOICHIOMETRIC MIXTURES |
690 | 1 | 0 | |a STRUCTURAL AND MAGNETIC PROPERTIES |
690 | 1 | 0 | |a YOUNG MODULUS |
690 | 1 | 0 | |a ASSOCIATION REACTIONS |
690 | 1 | 0 | |a CALCINATION |
690 | 1 | 0 | |a ENERGY DISPERSIVE SPECTROSCOPY |
690 | 1 | 0 | |a MAGNETIC ANISOTROPY |
690 | 1 | 0 | |a MAGNETIC FIELDS |
690 | 1 | 0 | |a MAGNETIC MOMENTS |
690 | 1 | 0 | |a MAGNETIZATION |
690 | 1 | 0 | |a METAL NANOPARTICLES |
690 | 1 | 0 | |a NEEDLES |
690 | 1 | 0 | |a SCANNING ELECTRON MICROSCOPY |
690 | 1 | 0 | |a SILICONES |
690 | 1 | 0 | |a SYNTHESIS (CHEMICAL) |
690 | 1 | 0 | |a X RAY DIFFRACTION |
690 | 1 | 0 | |a NANOMAGNETICS |
700 | 1 | |a Mietta, J.L. | |
700 | 1 | |a Soledad Antonel, P. | |
700 | 1 | |a Pérez, O.E. | |
700 | 1 | |a Martín Negri, R. | |
700 | 1 | |a Jorge, Guillermo Antonio | |
773 | 0 | |d 2013 |g v. 327 |h pp. 11-19 |p J Magn Magn Mater |x 03048853 |w (AR-BaUEN)CENRE-5651 |t Journal of Magnetism and Magnetic Materials | |
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856 | 4 | 0 | |u https://doi.org/10.1016/j.jmmm.2012.09.020 |y DOI |
856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_03048853_v327_n_p11_Ruiz |y Handle |
856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03048853_v327_n_p11_Ruiz |y Registro en la Biblioteca Digital |
961 | |a paper_03048853_v327_n_p11_Ruiz |b paper |c PE | ||
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999 | |c 72739 |