Temperature response of luminescent tris(bipyridine)ruthenium(II)-doped silica nanoparticles

Nanoparticle-based temperature imaging is an emerging field of advanced applications. Herein, the sensitivity of the phosphorescence of tris(bipyridine)ruthenium(II)-doped silica nanoparticles towards temperature is studied. 130nm size particles were prepared by a modification of Stöber's metho...

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Detalles Bibliográficos
Autor principal: Mirenda, M.
Otros Autores: Levi, V., Bossi, M.L, Bruno, Luciana, Bordoni, A.V, Regazzoni, A.E, Wolosiuk, A.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2013
Materias:
PH
Acceso en línea:Registro en Scopus
DOI
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
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024 7 |2 cas  |a oxygen, 7782-44-7; ruthenium, 7440-18-8; silicon dioxide, 10279-57-9, 14464-46-1, 14808-60-7, 15468-32-3, 60676-86-0, 7631-86-9; 2,2'-Dipyridyl, 551W113ZEP; Silicon Dioxide, 7631-86-9; tris(2,2'-bipyridine)ruthenium II, 15158-62-0 
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040 |a Scopus  |b spa  |c AR-BaUEN  |d AR-BaUEN 
100 1 |a Mirenda, M. 
245 1 0 |a Temperature response of luminescent tris(bipyridine)ruthenium(II)-doped silica nanoparticles 
260 |c 2013 
270 1 0 |m Regazzoni, A.E.; Gerencia Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, B1650KNA San Martín, Buenos Aires, Argentina; email: regazzon@cnea.gov.ar 
504 |a Vetrone, F., Naccache, R., Zamarrón, A., De La Fuente, A.J., Sanz-Rodríguez, F., Maestro, L.M., Rodriguez, E.M., Capobianco, J.A., (2010) ACS Nano, 4, pp. 3254-3258 
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506 |2 openaire  |e Política editorial 
520 3 |a Nanoparticle-based temperature imaging is an emerging field of advanced applications. Herein, the sensitivity of the phosphorescence of tris(bipyridine)ruthenium(II)-doped silica nanoparticles towards temperature is studied. 130nm size particles were prepared by a modification of Stöber's method, that allows the incorporation of Ru[(bpy)3]2+ into the outer particle shell. The entrapped Ru[(bpy)3]2+ retains its photophysical properties, yet the emission of the particles is not affected by the presence of O2, neither by anionic quenchers; quenching by MV2+, on the other hand, is strongly dependent on pH. Between 20 and 60°C, the steady-state emission of the particles decreases linearly with increasing temperature. The slope of the straight line diminishes slightly on thermal cycling, but soon stabilizes. Fluorescence measurements by scanning confocal microscopy indicate that the silica nanoparticles doped with Ru[(bpy)3]2+ can indeed be employed to probe thermal processes in micro-environments. © 2012 Elsevier Inc.  |l eng 
593 |a Gerencia Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, B1650KNA San Martín, Buenos Aires, Argentina 
593 |a Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, C1428EHA Buenos Aires, Argentina 
593 |a Laboratorio de Dinámica Intracelular, Departamento de Química Biológica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, C1428EHA Buenos Aires, Argentina 
593 |a Grupo de Dinámica y Transporte Intracelular, Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pab. I, C1428EHA Buenos Aires, Argentina 
650 1 7 |2 spines  |a PH 
690 1 0 |a DOPED SILICA 
690 1 0 |a FLUORESCENCE QUENCHING 
690 1 0 |a FLUORESCENT NANOPARTICLES 
690 1 0 |a LUMINESCENT TEMPERATURE NANOSENSORS 
690 1 0 |a TRIS(BIPYRIDINE)RUTHENIUM(II) 
690 1 0 |a ADVANCED APPLICATIONS 
690 1 0 |a BIPYRIDINES 
690 1 0 |a FLUORESCENCE MEASUREMENTS 
690 1 0 |a FLUORESCENCE QUENCHING 
690 1 0 |a FLUORESCENT NANOPARTICLES 
690 1 0 |a MICROENVIRONMENTS 
690 1 0 |a PHOTOPHYSICAL PROPERTIES 
690 1 0 |a SCANNING CONFOCAL MICROSCOPY 
690 1 0 |a SILICA NANOPARTICLES 
690 1 0 |a STEADY-STATE EMISSIONS 
690 1 0 |a TEMPERATURE IMAGING 
690 1 0 |a TEMPERATURE RESPONSE 
690 1 0 |a THERMAL PROCESS 
690 1 0 |a CONFOCAL MICROSCOPY 
690 1 0 |a FLUORESCENCE 
690 1 0 |a NANOPARTICLES 
690 1 0 |a QUENCHING 
690 1 0 |a SILICA 
690 1 0 |a RUTHENIUM 
690 1 0 |a ANION 
690 1 0 |a NANOPARTICLE 
690 1 0 |a OXYGEN 
690 1 0 |a RUTHENIUM 
690 1 0 |a SILICON DIOXIDE 
690 1 0 |a ARTICLE 
690 1 0 |a CONFOCAL MICROSCOPY 
690 1 0 |a FLUORESCENCE ANALYSIS 
690 1 0 |a LUMINESCENCE 
690 1 0 |a MICROENVIRONMENT 
690 1 0 |a PARTICLE SIZE 
690 1 0 |a PRIORITY JOURNAL 
690 1 0 |a SCANNING CONFOCAL MICROSCOPY 
690 1 0 |a SENSITIVITY ANALYSIS 
690 1 0 |a STEADY STATE 
690 1 0 |a TEMPERATURE DEPENDENCE 
690 1 0 |a THERMAL ANALYSIS 
690 1 0 |a 2,2'-DIPYRIDYL 
690 1 0 |a LUMINESCENCE 
690 1 0 |a MOLECULAR STRUCTURE 
690 1 0 |a NANOPARTICLES 
690 1 0 |a PARTICLE SIZE 
690 1 0 |a SILICON DIOXIDE 
690 1 0 |a SURFACE PROPERTIES 
690 1 0 |a TEMPERATURE 
700 1 |a Levi, V. 
700 1 |a Bossi, M.L. 
700 1 |a Bruno, Luciana 
700 1 |a Bordoni, A.V. 
700 1 |a Regazzoni, A.E. 
700 1 |a Wolosiuk, A. 
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