Co-biosorption of copper and glyphosate by Ulva lactuca
This study investigated the adsorption of glyphosate (PMG) onto the green algae Ulva lactuca. PMG was not adsorbed by U. lactuca but PMG was adsorbed when the process was mediated by Cu(II) with molar ratios Cu(II):PMG ≥ 1.5:1.U. lactuca was characterized by water adsorption surface area, FTIR, SEM...
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2013
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| LEADER | 10799caa a22016337a 4500 | ||
|---|---|---|---|
| 001 | PAPER-11579 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518204144.0 | ||
| 008 | 190411s2013 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-84873208934 | |
| 024 | 7 | |2 cas |a copper, 15158-11-9, 7440-50-8; glyphosate, 1071-83-6; Copper, 789U1901C5; Glycine, TE7660XO1C; Herbicides; Water, 059QF0KO0R; glyphosate, 1071-83-6 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a CSBBE | ||
| 100 | 1 | |a Trinelli, M.A. | |
| 245 | 1 | 0 | |a Co-biosorption of copper and glyphosate by Ulva lactuca |
| 260 | |c 2013 | ||
| 270 | 1 | 0 | |m Dos Santos Afonso, M.; INQUIMAE and Dept. de Química Inorgánica, Analítica y Quimica Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria Pabellón II 3er Piso, C1428EHA Buenos Aires, Argentina; email: dosantos@qi.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a This study investigated the adsorption of glyphosate (PMG) onto the green algae Ulva lactuca. PMG was not adsorbed by U. lactuca but PMG was adsorbed when the process was mediated by Cu(II) with molar ratios Cu(II):PMG ≥ 1.5:1.U. lactuca was characterized by water adsorption surface area, FTIR, SEM and EDS. The Langmuir and Freundlich models were applied. Results showed that the biosorption processes for copper and PMG in the presence of copper were described described by the Langmuir model (qmax=0.85±0.09mmolg-1, KL=0.55±0.14lmmol-1 and qmax=3.65±0.46mmolg-1, KL=0.103±0.03lmmol-1, respectively). Copper adsorption was greater in the presence of PMG than in the absence of the pesticide and the adsorption can only be represented by the Freundlich model (KF=0.08±0.01, 1/n=1.86±0.07).In all cases studied, the maximum metal uptake (qmax) increased with increasing pH. Surface complexes with a stoichiometry ranging from CuPMGCu to CuPMGCu3 are suggested as reaction products of the process.Due to the increasing amounts of PMG applied in Argentina, natural reservoirs present considerable amounts of this herbicide. The value of this work resides in using U. lactuca, a marine seaweed commonly found along coastlines all over the world, as a biosorbent for PMG. © 2013 Elsevier B.V. |l eng | |
| 593 | |a INQUIMAE and Dept. de Química Inorgánica, Analítica y Quimica Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria Pabellón II 3er Piso, C1428EHA Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a BIOSORPTION |
| 690 | 1 | 0 | |a COPPER |
| 690 | 1 | 0 | |a GLYPHOSATE |
| 690 | 1 | 0 | |a ULVA LACTUCA |
| 690 | 1 | 0 | |a BIOSORBENTS |
| 690 | 1 | 0 | |a BIOSORPTION PROCESS |
| 690 | 1 | 0 | |a COPPER ADSORPTION |
| 690 | 1 | 0 | |a FREUNDLICH MODELS |
| 690 | 1 | 0 | |a FTIR |
| 690 | 1 | 0 | |a GLYPHOSATES |
| 690 | 1 | 0 | |a GREEN ALGA |
| 690 | 1 | 0 | |a LANGMUIR MODELS |
| 690 | 1 | 0 | |a LANGMUIRS |
| 690 | 1 | 0 | |a METAL UPTAKE |
| 690 | 1 | 0 | |a MOLAR RATIO |
| 690 | 1 | 0 | |a SURFACE AREA |
| 690 | 1 | 0 | |a SURFACE COMPLEX |
| 690 | 1 | 0 | |a ULVA LACTUCA |
| 690 | 1 | 0 | |a WATER ADSORPTION |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a ALGAE |
| 690 | 1 | 0 | |a BIOSORPTION |
| 690 | 1 | 0 | |a COPPER |
| 690 | 1 | 0 | |a RESERVOIRS (WATER) |
| 690 | 1 | 0 | |a STOICHIOMETRY |
| 690 | 1 | 0 | |a HERBICIDES |
| 690 | 1 | 0 | |a COPPER |
| 690 | 1 | 0 | |a GLYPHOSATE |
| 690 | 1 | 0 | |a HERBICIDE |
| 690 | 1 | 0 | |a METAL ION |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a BINDING SITE |
| 690 | 1 | 0 | |a BIOSORPTION |
| 690 | 1 | 0 | |a CALCULATION |
| 690 | 1 | 0 | |a CELL WALL |
| 690 | 1 | 0 | |a COMPLEX FORMATION |
| 690 | 1 | 0 | |a CONTROLLED STUDY |
| 690 | 1 | 0 | |a INFRARED SPECTROSCOPY |
| 690 | 1 | 0 | |a ISOTHERM |
| 690 | 1 | 0 | |a NONHUMAN |
| 690 | 1 | 0 | |a PRIORITY JOURNAL |
| 690 | 1 | 0 | |a STOICHIOMETRY |
| 690 | 1 | 0 | |a SURFACE PROPERTY |
| 690 | 1 | 0 | |a ULVA |
| 690 | 1 | 0 | |a ADSORPTION |
| 690 | 1 | 0 | |a BIOMASS |
| 690 | 1 | 0 | |a COPPER |
| 690 | 1 | 0 | |a GLYCINE |
| 690 | 1 | 0 | |a HERBICIDES |
| 690 | 1 | 0 | |a HYDROGEN-ION CONCENTRATION |
| 690 | 1 | 0 | |a SPECTROPHOTOMETRY, INFRARED |
| 690 | 1 | 0 | |a ULVA |
| 690 | 1 | 0 | |a WATER |
| 651 | 4 | |a ARGENTINA | |
| 650 | 1 | 7 | |2 spines |a PH |
| 700 | 1 | |a Areco, M.M. | |
| 700 | 1 | |a Dos Santos Afonso, M. | |
| 773 | 0 | |d 2013 |g v. 105 |h pp. 251-258 |p Colloids Surf. B Biointerfaces |x 09277765 |w (AR-BaUEN)CENRE-4236 |t Colloids and Surfaces B: Biointerfaces | |
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| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_09277765_v105_n_p251_Trinelli |y Handle |
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