Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a Li-air battery

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In situ infrared subtractive normalized Fourier transform infrared spectroscopy (SNIFTIRS) experiments performed simultaneously with the electroreduction of oxygen on gold and platinum cathodes in LiPF6 dimethyl sulfoxide (DMSO) electrolyte have shown that the solvent is stable with respect to nucle...

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Autor principal: Mozhzhukhina, N.
Otros Autores: Méndez De Leo, L.P, Calvo, E.J
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2013
Acceso en línea:Registro en Scopus
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100 1 |a Mozhzhukhina, N. 
245 1 0 |a Infrared spectroscopy studies on stability of dimethyl sulfoxide for application in a Li-air battery 
260 |c 2013 
270 1 0 |m Calvo, E.J.; INQUIMAE, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, AR-1428 Buenos Aires, Argentina; email: calvo@qi.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
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504 |a Christensen, J., Albertus, P., Sanchez-Carrera, R.S., Lohmann, T., Kozinsky, B., Liedtke, R., Ahmed, J., Kojic, A., A Critical Review of Li/Air Batteries (2012) J. Electrochem. Soc., 159, p. 1 
504 |a Choi, N.S., Chen, Z., Freunberger, S.A., Ji, X., Sun, Y.K., Amine, K., Yushin, G., Bruce, P.G., Challenges facing lithium batteries and electrical double-layer capacitors (2012) Angew. Chem., Int. Ed. Engl., 51, pp. 9994-10024 
504 |a Peng, Z., Freunberger, S.A., Hardwick, L.J., Chen, Y., Giordani, V., Barde, F., Novak, P., Bruce, P.G., Oxygen reactions in a non-aqueous Li+ electrolyte (2011) Angew. Chem., Int. Ed. Engl., 50, pp. 6351-6355 
504 |a Laoire, C.O., Mukerjee, S., Abraham, K.M., Plichta, E.J., Hendrickson, M.A., (2009) J. Phys. Chem. C, 113, pp. 20127-20134 
504 |a McCloskey, B.D., Speidel, A., Scheffler, R., Miller, D.C., Viswanathan, V., Hummelshoj, J.S., Norskov, J.K., Luntz, A.C., (2012) J. Phys. Chem. Lett., 3, pp. 997-1001 
504 |a McCloskey, B.D., Scheffler, R., Speidel, A., Girishkumar, G., Luntz, A.C., On the Mechanism of Nonaqueous Li-O2 Electrochemistry on C and Its Kinetic Overpotentials: Some Implications for Li-Air Batteries (2012) J. Phys. Chem. C, 116, pp. 23897-23905 
504 |a Freunberger, S.A., Chen, Y., Peng, Z., Griffin, J.M., Hardwick, L.J., Barde, F., Novak, P., Bruce, P.G., Reactions in the Rechargeable Lithium-O2 Battery with Alkyl Carbonate Electrolytes (2011) J. Am. Chem. Soc., 133, pp. 8040-8047 
504 |a Xu, D., Wang, Z.-L., Xu, J.-J., Zhang, L.-L., Zhang, X.-B., Novel DMSO-based electrolyte for high performance rechargeable Li-O 2 batteries (2012) Chem. Commun., 48, pp. 6948-6950 
504 |a Wang, H., Xie, K., Investigation of oxygen reduction chemistry in ether and carbonate based electrolytes for Li-O2 batteries (2012) Electrochim. Acta, 64, pp. 29-34 
504 |a McCloskey, B.D., Bethune, D.S., Shelby, R.M., Girishkumar, G., Luntz, A.C., Solvents' Critical Role in Nonaqueous Lithium-Oxygen Battery Electrochemistry (2011) J. Phys. Chem. Lett., 2, pp. 1161-1166 
504 |a Freunberger, S.A., Chen, Y., Drewett, N.E., Hardwick, L.J., Barde, F., Bruce, P.G., The lithium-oxygen battery with ether-based electrolytes (2011) Angew. Chem., Int. Ed., 50, pp. 8609-8613 
504 |a Laoire, C.O., Mukerjee, S., Abraham, K.M., Plichta, E.J., Hendrickson, M.A., Influence of Nonaqueous Solvents on the Electrochemistry of Oxygen in the Rechargeable Lithium-Air Battery (2010) J. Phys. Chem. C, 114, pp. 9178-9186 
504 |a Peng, Z., Freunberger, S.A., Chen, Y., Bruce, P.G., A reversible and higher-rate Li-O2 battery (2012) Science, 337, pp. 563-566 
504 |a Trahan, M.J., Mukerjee, S., Plichta, E.J., Hendrickson, M.A., Abraham, K.M., Studies of Li-Air Cells Utilizing Dimethyl Sulfoxide-Based Electrolyte (2013) J. Electrochem. Soc., 160, pp. 259-A267 
504 |a Calvo, E.J., Mozhzhukhina, N., A Rotating Ring Disk Electrode Study of the Oxygen Reduction Reaction in Lithium Containing Non Aqueous Electrolyte (2013) Electrochem. Commun., 31, pp. 56-58 
504 |a Goolsby, A.D., Sawyer, D.T., The Electrochemical Reduction of Superoxide Ion and Oxidation of Hydroxide Ion in Dimethyl Sulfoxide (1968) Anal. Chem., 40, pp. 83-86 
504 |a Gampp, H., Lippard, S.J., Reinvestigation of 18-Crown-6 Ether/Potassium Superoxide Solutions in Me2SO (1983) Inorg. Chem., 22, pp. 357-358 
504 |a Krtil, P., Kavan, L., Hoskovcova, I., Kratochvilova, K., Anodic oxidation of dimethyl sulfoxide based electrolyte solutions: An in situ FTIR study (1996) J. Appl. Electrochem., 26, pp. 523-527 
504 |a Bellamy, L.J., (1954) The Infra-red Spectra of Complex Molecules, , Methuen & Co Ltd. London 
504 |a Lin-Vein, D., Colthup, N.B., Fateley, W.G., Grasselli, J.G., (1991) The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules, , Academic Press, Inc. San Diego, CA 
504 |a http://webbook.nist.gov/chemistry/, NIST Chemistry WebBook: NIST Standard Reference Database Number 69. National Institute of Standards and Technology 
520 3 |a In situ infrared subtractive normalized Fourier transform infrared spectroscopy (SNIFTIRS) experiments performed simultaneously with the electroreduction of oxygen on gold and platinum cathodes in LiPF6 dimethyl sulfoxide (DMSO) electrolyte have shown that the solvent is stable with respect to nucleophilic attack by the electrogenerated superoxide radical anion. However, long-term experiments with KO2 solutions in DMSO have shown a slow formation of dimethyl sulfone. Evidence of dimethyl sulfone formation by anodic oxidation of DMSO above 4.2 V (Li/Li+) in the presence of trace water has been obtained on gold. On platinum, this unwanted reaction in the charging cycle of a lithium-air battery takes place at lower potentials, i.e., 3.5 V. © 2013 American Chemical Society.  |l eng 
593 |a INQUIMAE, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, AR-1428 Buenos Aires, Argentina 
690 1 0 |a DIMETHYL SULFOXIDE (DMSO) 
690 1 0 |a ELECTROREDUCTION OF OXYGENS 
690 1 0 |a LITHIUM-AIR BATTERY 
690 1 0 |a LONG-TERM EXPERIMENTS 
690 1 0 |a NUCLEOPHILIC ATTACK 
690 1 0 |a OXIDATION OF DMSO 
690 1 0 |a PLATINUM CATHODES 
690 1 0 |a SUPEROXIDE RADICAL ANIONS 
690 1 0 |a ANODIC OXIDATION 
690 1 0 |a CHARGING (BATTERIES) 
690 1 0 |a DIMETHYL SULFOXIDE 
690 1 0 |a ELECTROLYTIC REDUCTION 
690 1 0 |a EXPERIMENTS 
690 1 0 |a FOURIER TRANSFORM INFRARED SPECTROSCOPY 
690 1 0 |a GOLD 
690 1 0 |a LITHIUM 
690 1 0 |a ORGANIC SOLVENTS 
690 1 0 |a OXYGEN 
690 1 0 |a PLATINUM 
690 1 0 |a LITHIUM BATTERIES 
700 1 |a Méndez De Leo, L.P. 
700 1 |a Calvo, E.J. 
773 0 |d 2013  |g v. 117  |h pp. 18375-18380  |k n. 36  |p J. Phys. Chem. C  |x 19327447  |t Journal of Physical Chemistry C 
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856 4 0 |u https://doi.org/10.1021/jp407221c  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_19327447_v117_n36_p18375_Mozhzhukhina  |y Handle 
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