Mineralization and efficiency in the homogeneous Fenton Orange G oxidation

This study focuses on the homogeneous Fenton oxidation of the synthetic azo-dye Orange G as a model compound. The impact of initial TOC, hydrogen peroxide and catalyst concentrations and of temperature on mineralization and efficiency in the use of hydrogen peroxide is addressed. Dissolved oxygen co...

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Detalles Bibliográficos
Autor principal: Doumic, L.I
Otros Autores: Haure, P.M, Cassanello, M.C, Ayude, M.A
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2013
Acceso en línea:Registro en Scopus
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030 |a ACBEE 
100 1 |a Doumic, L.I. 
245 1 0 |a Mineralization and efficiency in the homogeneous Fenton Orange G oxidation 
260 |c 2013 
270 1 0 |m Ayude, M.A.; Catalizadores y Superficies, INTEMA-CONICET, Facultad de Ingeniería, UNMdP, J.B. Justo 4302, 7600 Mar del Plata, Argentina; email: mayude@fi.mdp.edu.ar 
506 |2 openaire  |e Política editorial 
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504 |a Arslan Alaton, I., Teksoy, S., (2007) Dyes and Pigments, 73, pp. 31-39 
504 |a Ramirez, J.H., Duarte, F.M., Martins, F.G., Costa, C.A., Madeira, L.M., (2009) Chemical Engineering Journal, 148, pp. 394-404 
504 |a Wu, Y., Zhou, S., Zheng, K., Ye, X., Qin, F., (2011) Waste Management, 31, pp. 468-474 
504 |a (1993) Measurement of Oxygen Transfer in Clean Water, , ASCE Publications, USA American Society of Civil Engineers 
504 |a Sun, S., Li, C., Sun, J., Shi, S., Fan, M., Zhou, Q., (2009) Journal of Hazardous Materials, 161, pp. 1052-1057 
504 |a Gallard, H., de Laat, J., Legube, B., (1998) New Journal of Chemistry, 22, pp. 263-268 
504 |a Ramirez, J.H., Costa, C.A., Madeira, L.M., (2005) Catalysis Today, pp. 68-76 
504 |a Burbano, A.A., Dionysiou, D.D., Suidan, M.T., Richardson, T.L., (2005) Water Research, 39, pp. 107-118 
504 |a Bach, A., Shemer, H., Semiat, R., (2010) Desalination, 264, pp. 188-192 
504 |a Zazo, J.A., Pliego, G., Blasco, S., Casas, J.A., Rodríguez, J.J., (2011) Industrial and Engineering Chemistry Research, 50, pp. 866-870 
504 |a (2012) R: A Language and Environment for Statistical Computing, , http://www.r-project.org/, R Foundation for Statistical Computing, Vienna, Austria R Core Team 
520 3 |a This study focuses on the homogeneous Fenton oxidation of the synthetic azo-dye Orange G as a model compound. The impact of initial TOC, hydrogen peroxide and catalyst concentrations and of temperature on mineralization and efficiency in the use of hydrogen peroxide is addressed. Dissolved oxygen concentration is monitored as an indication of the efficient use of H2O2 in the process. A two-stage lumped kinetic model is proposed to address the effect of initial TOC, catalyst and oxidant concentrations and temperature on total organic carbon consumption. Temperature increase and dosification of the oxidant are evaluated and compared as process intensification strategies. © 2013 Elsevier B.V.  |l eng 
536 |a Detalles de la financiación: Universidad de Buenos Aires 
536 |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas 
536 |a Detalles de la financiación: Financial support from CONICET , UBA , UNMdP and ANPCyT are gratefully acknowledged. We want to express our gratitude to C. Rodriguez and H. Asencio for their technical support. The authors would also like to thank the reviewers for their careful reading and helpful comments. 
593 |a Catalizadores y Superficies, INTEMA-CONICET, Facultad de Ingeniería, UNMdP, J.B. Justo 4302, 7600 Mar del Plata, Argentina 
593 |a PINMATE, Dep. Industrias, FCEyN, Universidad de Buenos Aires, Intendente Güiraldes 2620, C1428BGA Buenos Aires, Argentina 
690 1 0 |a AZO DYE 
690 1 0 |a FENTON OXIDATION 
690 1 0 |a INTENSIFICATION PROCESS 
690 1 0 |a CATALYST CONCENTRATION 
690 1 0 |a DISSOLVED OXYGEN CONCENTRATIONS 
690 1 0 |a FENTON OXIDATION 
690 1 0 |a INTENSIFICATION PROCESS 
690 1 0 |a LUMPED KINETIC MODELS 
690 1 0 |a OXIDANT CONCENTRATIONS 
690 1 0 |a PROCESS INTENSIFICATION STRATEGY 
690 1 0 |a TEMPERATURE INCREASE 
690 1 0 |a AZO DYES 
690 1 0 |a CATALYSTS 
690 1 0 |a HYDROGEN PEROXIDE 
690 1 0 |a MINERALOGY 
690 1 0 |a OXIDANTS 
690 1 0 |a PEROXIDES 
690 1 0 |a OXIDATION 
700 1 |a Haure, P.M. 
700 1 |a Cassanello, M.C. 
700 1 |a Ayude, M.A. 
773 0 |d 2013  |g v. 142-143  |h pp. 214-221  |p Appl. Catal. B Environ.  |x 09263373  |w (AR-BaUEN)CENRE-3757  |t Applied Catalysis B: Environmental 
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856 4 0 |u https://hdl.handle.net/20.500.12110/paper_09263373_v142-143_n_p214_Doumic  |y Handle 
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