Reactions of nitroanisoles. Part 6. Reaction of 2,6-dinitroanisole with cyclohexylamine in mixed solvents. Solvent evidence for the 'dimer' mechanism

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The reaction of 2,6-dinitroanisole with cyclohexylamine in methanol and benzene-methanol was studied at several amine concentrations. Although the reaction rate in methanol is higher than in benzene, addition of small amounts of methanol to the benzene solution diminishes the rate of reaction (which...

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Detalles Bibliográficos
Autor principal: Nudelman, N.S
Otros Autores: Palleros, D.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1984
Acceso en línea:Registro en Scopus
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100 1 |a Nudelman, N.S. 
245 1 0 |a Reactions of nitroanisoles. Part 6. Reaction of 2,6-dinitroanisole with cyclohexylamine in mixed solvents. Solvent evidence for the 'dimer' mechanism 
260 |c 1984 
270 1 0 |m Nudelman, N.S.; Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pab. II, 1428 Buenos Aires, Argentina 
506 |2 openaire  |e Política editorial 
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520 3 |a The reaction of 2,6-dinitroanisole with cyclohexylamine in methanol and benzene-methanol was studied at several amine concentrations. Although the reaction rate in methanol is higher than in benzene, addition of small amounts of methanol to the benzene solution diminishes the rate of reaction (which is of third order in amine), reaching a minimum value at nearly 30% methanol, after which the rate increases almost linearly with the methanol content. These and other results, here described, are satisfactorily explained by a previously proposed reaction scheme, in which the dimer of the amine is operating.  |l eng 
593 |a Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pab. II, 1428 Buenos Aires, Argentina 
700 1 |a Palleros, D. 
773 0 |d 1984  |h pp. 1277-1280  |k n. 8  |x 1472779X  |t Journal of the Chemical Society, Perkin Transactions 2 
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