Luminescent Eu(III) hybrid sensors for in situ copper detection
In this work we used the sol-gel technique to develop luminescent Eu(III) transparent films deposited on glass slides to build for sensor devices capable of monitoring transition metal ions in aqueous solutions. The films were obtained from a bis(trialkoxysilyl) organic precursor synthesized from th...
Guardado en:
| Autor principal: | |
|---|---|
| Otros Autores: | , , , |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
2011
|
| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 18589caa a22015377a 4500 | ||
|---|---|---|---|
| 001 | PAPER-10155 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518204010.0 | ||
| 008 | 190411s2011 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-79960449536 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a SABCE | ||
| 100 | 1 | |a Barja, B.C. | |
| 245 | 1 | 0 | |a Luminescent Eu(III) hybrid sensors for in situ copper detection |
| 260 | |c 2011 | ||
| 270 | 1 | 0 | |m Barja, B.C.; INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, C1428EHA Buenos Aires, Argentina; email: barja@qi.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Yoshina-Ishii, C., Asefa, T., Coombs, N., MacLachlan, M.J., Ozin, G.A., Periodic mesoporous organosilicas, PMOs: Fusion of organic and inorganic chemistry 'inside' the channel walls of hexagonal mesoporous silica (1999) Chemical Communications, (24), pp. 2539-2540 | ||
| 504 | |a Baney, R.H., Itoh, M., Sakakibara, A., Suzuki, T., Silsesquioxanes (1995) Chem. Rev., 95, pp. 1409-1430 | ||
| 504 | |a Beck, J.S., Vartuli, J.C., Roth, W.J., Leonowicz, M.E., Kresge, C.T., Schmitt, K.D., Chu, C.T.W., Schlenker, J.L., (1992) J. Am. Chem. Soc., 114, p. 10834 | ||
| 504 | |a Melde, B.J., Holland, B.T., Blanford, C.F., Stein, A., Mesoporous sieves with unified hybrid inorganic/organic frameworks (1999) Chemistry of Materials, 11 (11), pp. 3302-3308 | ||
| 504 | |a Tani, T., Mizoshitaab, N., Inagaki, S., Luminescent periodic mesoporous organosilicas (2009) J. Mater. Chem., 19, pp. 4451-4456 | ||
| 504 | |a Benson, E., Medí, A., Reyé, C., Corriú, R.J.P., Functionalisation of the framework of mesoporous organisilicas by rare-earth complexes (2006) Mater. Chem., 16, pp. 246-248 | ||
| 504 | |a Manuela Silva, M., De Zea Bermudez, V., Carlos, L.D., Passos De Almeida, A., Smith, M.J., Sol-gel processing and structural study of europium-doped hybrid materials (1999) J. Mater. Chem., 9, pp. 1735-1740 | ||
| 504 | |a Corriu, R.J.P., Mehdi, A., Reye, C., Thieuleux, C., Control of coordination chemistry in both the framework and the pore channels of mesoporous hybrid materials (2003) New Journal of Chemistry, 27 (6), pp. 905-908. , DOI 10.1039/b302027d | ||
| 504 | |a Binnemans, K., Lanthanide-based luminescent hybrid materials (2009) Chem. Rev., 109, pp. 4283-4374 | ||
| 504 | |a Carlos, L.D., Ferreira, R.A.S., De Zea Bermudez, V., Ribeiro, S.J.L., Lanthanide-containing light-emitting organic-inorganic hybrids: A bet on the future (2009) Adv. Mater., 21, pp. 509-534 | ||
| 504 | |a Ofelt, G.S., Structure of the f6 configuration with application to rare earth ions (1963) J. Chem. Phys., 38, pp. 2171-2180 | ||
| 504 | |a Parker, D., Excitement in f block: Structure, dynamics and function of nine-coordinate chiral lanthanide complexes in aqueous media (2004) Chemical Society Reviews, 33 (3), pp. 156-165. , DOI 10.1039/b311001j | ||
| 504 | |a Parker, D., Dickins, R.S., Puschmann, H., Crossland, C., Howard, J.A.K., Being excited by lanthanide coordination complexes: Aqua species, chirality, excited-state chemistry, and exchange dynamics (2002) Chemical Reviews, 102 (6), pp. 1977-2010. , DOI 10.1021/cr010452+ | ||
| 504 | |a Peacock, R.D., The intensities of lanthanide f-f transitions (1975) Struct. Bonding, 22, pp. 83-122 | ||
| 504 | |a Chen, J., Selvin, P.R., Synthesis of 7-amino-4-trifluoromethyl-2-(1H)-quinolinone and its use as an antenna molecule for the luminescent europium polyaminocarboxylates chelates (2000) J. Photochem. Photobiol. A, 135, pp. 27-32 | ||
| 504 | |a Ge, P., Selvin, P.R., Carbostyril derivatives as antenna molecules for luminescent lanthanide chelates (2004) Bioconjugate Chemistry, 15 (5), pp. 1088-1094. , DOI 10.1021/bc049915j | ||
| 504 | |a Li, M., Selvin, P.R., Luminescent polyaminocarboxylate chelates of terbium and europium: The effect of chelate structure (1995) J. Am. Chem. Soc., 117, pp. 8132-8138 | ||
| 504 | |a Bunzli, J.-C.G., Comby, S., Chauvin, A.-S., Vandevyver, C.D.B., New Opportunities for Lanthanide Luminescence (2007) Journal of Rare Earths, 25 (3), pp. 257-274. , DOI 10.1016/S1002-0721(07)60420-7, PII S1002072107604207 | ||
| 504 | |a Gassner, A.-L., Duhot, C., Bünzli, J.-C.G., Chauvin, A.-S., Remarkable tuning of the photophysical properties of bifunctional lanthanide tris(dipicolinates) and its consequence on the design of bioprobes (2008) Inorg. Chem., 47, pp. 7802-7812 | ||
| 504 | |a Liu, T., Hu, J., Yin, J., Zhang, Y., Li, Ch., Liu, Sh., Enhancing detection sensitivity of responsive microgel-based Cu(II) chemosensors via thermo-induced volume phase transitions (2009) Chem. Mater., 21, pp. 3439-3446 | ||
| 504 | |a Wirnsberger, G., Scott, B.J., Stucky, G.D., PH sensing with mesoporous thin films (2001) Chemical Communications, (1), pp. 119-120 | ||
| 504 | |a Montalti, M., Prodi, L., Zaccheroni, N., Charbonniere, L., Douce, L., Ziessel, R., A luminescent anion sensor based on a europium hybrid complex (2001) Journal of the American Chemical Society, 123 (50), pp. 12694-12695. , DOI 10.1021/ja0118688 | ||
| 504 | |a Eliseevaa, S.V., Bünzli, J.-C.G., Lanthanide luminescence for functional materials and bio-sciences (2010) Chem. Soc. Rev., 39, pp. 189-227 | ||
| 504 | |a Brinker, C.J., Scherer, G.W., (1990) Sol-Gel Science, , The Physics and Chemistry of Sol-Gel Processing Ac. Press Inc | ||
| 504 | |a Reisfeld, R., Prospects of sol-gel technology towards luminescent materials (2001) Optical Materials, 16 (1-2), pp. 1-7. , DOI 10.1016/S0925-3467(00)00052-5 | ||
| 504 | |a Embert, F., Mahdi, A., Reyé, C., Corriú, R.J.P., Synthesis, Luminescent properties of monophasic organic-inorganic hybrid materials incorporating Europium(III) (2001) Chem. Mater., 13, pp. 4542-4549 | ||
| 504 | |a Franville, A.-C., Zambon, D., Mahiou, R., Luminescence behavior of sol-gel derived hybrid materials resulting from covalent grafting of a chromophore unit to different organically modified alkoxysilanes (2000) Chem. Mater., 12, pp. 428-435 | ||
| 504 | |a Liu, P., Li, H., Wang, Y., Liu, B., Zhang, W., Wang, Y., Yan, W., Schubert, U., Europium complexes immobilization on titania via chemical modification of titanium alkoxide (2008) Journal of Materials Chemistry, 18 (7), pp. 735-737. , DOI 10.1039/b717864f | ||
| 504 | |a Hernandez, R., Franville, A.-C., Minoofar, P., Dunn, B., Zink, J.I., Controlled placement of luminescent molecules and polymers in mesostructured sol-gel thin films [10] (2001) Journal of the American Chemical Society, 123 (6), pp. 1248-1249. , DOI 10.1021/ja003634e | ||
| 504 | |a Cousinié, S., Gressier, M., Reber, C., Dexpert-Ghys, J., Menu, M.-L., Europium(III) complexes containing organosilyldipyridine ligands grafted on silica nanoparticles (2008) Langmuir, 24, pp. 6208-6214 | ||
| 504 | |a Lobnik, A., Majcen, N., Niederreiter, K., Uray, G., Optical pH sensor based on the absorption of antenna generated europium luminescence by bromothymolblue in a sol-gel membrane (2001) Sensors and Actuators, B: Chemical, 74 (1-3), pp. 200-206. , DOI 10.1016/S0925-4005(00)00734-6, PII S0925400500007346 | ||
| 504 | |a Sommerdijk, N.A.J.M., Poppe, A., Gibson, C.A., Wright, J.D., Unexpected complexation behaviour of a sol-gel immobilised dye: The development of an optical copper (II) sensor (1998) Journal of Materials Chemistry, 8 (3), pp. 565-567 | ||
| 504 | |a Wright, J.D., Higginson, N.A.C., Effects of matrix variation on pH and Cu2+ sensing properties of sol-gel entrapped eriochrome cyanine R (2004) J. Mater. Chem., 14, pp. 201-208 | ||
| 504 | |a Selvin, P.R., Rana, T.M., Hearst, J.E., Luminescence resonance energy transfer (1994) Journal of the American Chemical Society, 116 (13), pp. 6029-6030 | ||
| 504 | |a Selvin, P.R., The renaissance of fluorescence resonance energy transfer (2000) Nat. Struct. Biol., 7, pp. 730-734 | ||
| 504 | |a Kessler, M.A., Determination of copper at ng ml-1-levels based on quenching of the europium chelate luminescence (1998) Analytica Chimica Acta, 364 (1-3), pp. 125-129. , DOI 10.1016/S0003-2670(98)00152-4, PII S0003267098001524 | ||
| 504 | |a Brayshaw, P., Bünzli, J.C.G., Froidenaux, P., Harrowfield, J.M., Kim, Y., Sobolev, A.N., Synthetic, structural, and spectroscopic studies on solids containing tris(dipicolinato) rare earth anions and transition or main group metal cations (1995) Inorg. Chem., 34, pp. 2068-2076 | ||
| 504 | |a Zhang, L., Li, B., Su, Zh., Yue, Sh., (2010) Sens. Actuators B Chem., pp. 595-599 | ||
| 504 | |a Chen, B., Wang, L., Xiao, Y., Fronczek, F.R., Xue, M., Cui, Y., Qian, G., (2009) Angew. Chem. Int. Ed., 48, pp. 500-503 | ||
| 504 | |a Valeur, B., Leray, I., Design principles of fluorescent molecular sensors for cation recognition (2000) Coord. Chem. Rev., 205, pp. 3-40 | ||
| 504 | |a Parker, D., Luminescent lanthanide sensors for pH, pO2 and selected anions (2000) Coord. Chem. Rev., 205, pp. 109-130 | ||
| 504 | |a Bojinov, V.B., Nikolai, I., Georgiev, Bosch, P., Design and synthesis of highly photostable yellow-green emitting 1,8-naphthalimides as fluorescent sensors for metal cations and protons (2009) J. Fluoresc., 19, pp. 127-139 | ||
| 504 | |a Wolfbeis, O.S., (1991) Fiber Optic Chemical Sensors and Biosensors, Vols. i and Ii, , CRC Press Boca Raton | ||
| 504 | |a Murray, G.M., Sarrio, R.V., Peterson, J.R., The effects of hydration on the luminescence spectra of the trisodium tris(2,6-pyridenedicarboxylato)europium(III) compounds (1990) Inorg. Chim. Acta, 176, pp. 233-240 | ||
| 504 | |a Franville, A.-C., Mahiou, R., Zambon, D., Cousseins, J.-C., Molecular design of luminescent organic-inorganic hybrid materials activated by europium (III) ions (2001) Solid State Sciences, 3 (1-2), pp. 211-222. , DOI 10.1016/S1293-2558(00)01114-6, PII S1293255800011146 | ||
| 504 | |a Barja, B.C., Aramendia, P.F., Luminescent Eu(III) hybrid materials for sensor applications (2008) Photochem. Photobiol. Sci., 7, pp. 1391-1399 | ||
| 504 | |a Minoofar, P.N., Dunn, B.S., Zink, J.I., Multiply doped nanostructured silicate sol-gel thin films: Spatial segregation of dopants, energy transfer, and distance measurements (2005) Journal of the American Chemical Society, 127 (8), pp. 2656-2665. , DOI 10.1021/ja045185e | ||
| 504 | |a Cui, H., Chen, J., Zhou, H., Lu, Y., Synthesis and infrared and fluorescent spectra of rare earth complexes with a new amide ligand (2007) Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 68 (3), pp. 478-483. , DOI 10.1016/j.saa.2006.12.060, PII S1386142506007372 | ||
| 504 | |a Wu, W.-N., Yuan, W.-B., Tang, N., Yang, R.-D., Yan, L., Xu, Z.-H., Synthesis, characterizations and luminescent properties of three novel aryl amide type ligands and their lanthanide complexes (2006) Spectrochim. Acta A, 65, pp. 912-991 | ||
| 504 | |a Roeges, N.P.G., (1994) A Guide to the Complete Interpretation of Infrared Spectra of Organic Structures, , John Wiley & Sons Ltd England | ||
| 504 | |a Reisfeld, R., Zigansky, E., Gaft, M., Europium probe for estimation of site symmetry in glass films, glasses and crystals (2004) Mol. Phys., 102, pp. 1319-1330 | ||
| 504 | |a Barja, B.C., Remorino, A., Roberti, M.J., Aramendia, P.F., Luminescence quenching of europium(III) and terbium carboxylates by transition metals in solution (2005) J. Argentine Chem. Soc., 4-6, pp. 81-96 | ||
| 504 | |a Anderegg, G., Pyridinderivate als Komplexbildner I. Pyridincarbonsauren Helv (1960) Chim. Acta, 43, pp. 414-424 | ||
| 504 | |a Anderegg, G., Pyridinderivate als Komplexbildner II. Komplexbildung des dreiwertigen Eisen-Ions mit Pyridincarbonsauren Helv (1960) Chim. Acta, 43, pp. 1530-1545 | ||
| 504 | |a Grenthe, I., (1963) J. Am. Chem. Soc., 83, p. 360 | ||
| 504 | |a Nishioka, T., Fukui, K., Matsumoto, K., Lanthanide chelates as luminescent labels in biomedical analysis (2007) Handbook on the Physics and Chemistry of Rare Earths, 37 VOL., pp. 71-215. , K.A. Gschneidner Jr. J.-C.G. Bünzli, V.K. Pecharsky, Elsevier V.B. Amsterdam Chapter 234 | ||
| 520 | 3 | |a In this work we used the sol-gel technique to develop luminescent Eu(III) transparent films deposited on glass slides to build for sensor devices capable of monitoring transition metal ions in aqueous solutions. The films were obtained from a bis(trialkoxysilyl) organic precursor synthesized from the amide of the 2,6-pyridinedicarboxylic acid (DPA) with aminopropyltriethoxysilane (APTES) in the presence or absence of cetyl trimethyl ammonium bromide (CTAB) surfactant as templating agent and triethylethoxysilane (TEOS) as crosslinker. These sensor devices were used to perform in situ quenching experiments by Cu(II), Fe(III), Co(II) and Ni(II) ions. The results indicate that the templated films allow the detection and quantification of these metals down to ppb levels by means of the values of the Stern-Volmer constants. In particular, it was shown that Cu(II) acts as an extremely efficient quencher (KSV = 3.5 × 105 M-1) when compared with the results obtained for the other metals, opening the possibility to use these devices as potential Cu(II) sensors for actual applications in aqueous media. © 2011 Elsevier B.V. Al rights reserved. |l eng | |
| 536 | |a Detalles de la financiación: Umweltbundesamt, PICT 10621, PIP 112-200801-02817, PIP 112-200801-02533 | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, X086 | ||
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica | ||
| 536 | |a Detalles de la financiación: S.E.B. and B.C.B. are members of Carrera del Investigador Científico (Research Staff) from CONICET (Consejo Nacional de Investigaciones Científicas y Técnicas, Argentina). We thank Prof. Pedro F. Aramendía for helpful discussions. The work was supported by grants X086 (UBA) , PIP 112-200801-02817 and PIP 112-200801-02533 ( CONICET , Argentina), and PICT 10621 (ANPCyT, Argentina). B.C. Barja is a member of the scientific staff of the Instituto de Química Fisica de los Materiales, Medio Ambiente y Energía, Consejo Nacional de Investigaciones Científicas y Técnicas (INQUIMAE/CONICET, Argentina). She obtained her PhD (Physical Chemistry area) at the University of Buenos Aires in 1999. Her research interests focus on the synthesis and development hybrid lanthanide-based luminescent materials with applications in sensing and photoactive materials. S.E. Bari is a member of the scientific staff of the Instituto de Química Fisica de los Materiales, Medio Ambiente y Energía, Consejo Nacional de Investigaciones Científicas y Técnicas (INQUIMAE/CONICET, Argentina). She holds a PhD degree in Organic Chemistry from the University of Buenos Aires (1991). Her expertise is related to the synthesis, spectroscopic characterization, and study of chemical reactivity of organic molecules and coordination complexes, with bioorganic or bioinorganic relevance. M.C. Marchi is a professor assistant of the Departamento de Química Inorgánica, Analítica y Química Fisica (DQIAyQF), Facultad de Ciencias Exactas y Naturales (FCEyN)–Universidad de Buenos Aires (UBA). She obtained her PhD (Physical Chemistry area) at the University of Buenos Aires in 2001. Her research interests focus on the synthesis of luminescent semiconductor particles embedded in oxide mesoporous materials to develop solar cells. She possesses large experience in the characterization of nanomaterials by microscopic techniques (TEM SEM). F. Iglesias is an advanced undergraduate student of the Licenciatura en Ciencias Químicas at the University of Buenos Aires, and has actively collaborated as members in the project X086 (UBA). M. Bernardi is an advanced undergraduate students of the Licenciatura en Ciencias Químicas at the University of Buenos Aires, and has actively collaborated as members in the project X086 (UBA). | ||
| 593 | |a INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, C1428EHA Buenos Aires, Argentina | ||
| 593 | |a Centro de Microscopías Avanzadas (CMA), Facultad de Ciencias Exactas y Naturales (FCEyN), Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 1, C1428EHA Buenos Aires, Argentina | ||
| 593 | |a Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, C1428EHA Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a CU(II) SENSOR |
| 690 | 1 | 0 | |a EUROPIUM(III) |
| 690 | 1 | 0 | |a HYBRID MATERIALS |
| 690 | 1 | 0 | |a LUMINESCENCE QUENCHING |
| 690 | 1 | 0 | |a SOL-GEL |
| 690 | 1 | 0 | |a AMINOPROPYLTRIETHOXYSILANE |
| 690 | 1 | 0 | |a AQUEOUS MEDIA |
| 690 | 1 | 0 | |a CETYLTRIMETHYLAMMONIUM BROMIDE |
| 690 | 1 | 0 | |a CROSSLINKER |
| 690 | 1 | 0 | |a GLASS SLIDES |
| 690 | 1 | 0 | |a IN-SITU |
| 690 | 1 | 0 | |a LUMINESCENCE QUENCHING |
| 690 | 1 | 0 | |a ORGANIC PRECURSOR |
| 690 | 1 | 0 | |a PPB LEVELS |
| 690 | 1 | 0 | |a SENSOR DEVICE |
| 690 | 1 | 0 | |a SOL-GEL TECHNIQUE |
| 690 | 1 | 0 | |a STERN-VOLMER CONSTANTS |
| 690 | 1 | 0 | |a TEMPLATED |
| 690 | 1 | 0 | |a TEMPLATING AGENTS |
| 690 | 1 | 0 | |a TRANSPARENT FILMS |
| 690 | 1 | 0 | |a AMIDES |
| 690 | 1 | 0 | |a AMMONIUM COMPOUNDS |
| 690 | 1 | 0 | |a BROMINE COMPOUNDS |
| 690 | 1 | 0 | |a EUROPIUM |
| 690 | 1 | 0 | |a GELS |
| 690 | 1 | 0 | |a GLASS TRANSITION |
| 690 | 1 | 0 | |a HYBRID MATERIALS |
| 690 | 1 | 0 | |a IRON COMPOUNDS |
| 690 | 1 | 0 | |a LUMINESCENCE |
| 690 | 1 | 0 | |a METAL IONS |
| 690 | 1 | 0 | |a QUENCHING |
| 690 | 1 | 0 | |a SILICON COMPOUNDS |
| 690 | 1 | 0 | |a SOL-GEL PROCESS |
| 690 | 1 | 0 | |a SOL-GELS |
| 690 | 1 | 0 | |a SOLS |
| 690 | 1 | 0 | |a SURFACE ACTIVE AGENTS |
| 690 | 1 | 0 | |a TRANSITION METALS |
| 690 | 1 | 0 | |a SENSORS |
| 700 | 1 | |a Bari, S.E. | |
| 700 | 1 | |a Marchi, M.C. | |
| 700 | 1 | |a Iglesias, F.L. | |
| 700 | 1 | |a Bernardi, M. | |
| 773 | 0 | |d 2011 |g v. 158 |h pp. 214-222 |k n. 1 |p Sens Actuators, B Chem |x 09254005 |w (AR-BaUEN)CENRE-6816 |t Sensors and Actuators, B: Chemical | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-79960449536&doi=10.1016%2fj.snb.2011.06.006&partnerID=40&md5=db08f86d10df52051c31e288e32ded87 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1016/j.snb.2011.06.006 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_09254005_v158_n1_p214_Barja |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09254005_v158_n1_p214_Barja |y Registro en la Biblioteca Digital |
| 961 | |a paper_09254005_v158_n1_p214_Barja |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 71108 | ||