Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine

The preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine was accomplished by oxydation of the unlabelled compound to tomatidone, exchange of the labile hydrogens by reaction with H20 and 3H2O on basic alumina and direct reduction of the labelled tomatidone to tomatidine. The efficiency of the procedure...

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Detalles Bibliográficos
Autor principal: Doller, D.
Otros Autores: Gros, E.G
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 1986
Acceso en línea:Registro en Scopus
DOI
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
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100 1 |a Doller, D. 
245 1 0 |a Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine 
260 |c 1986 
270 1 0 |m Doller, D.; Departamento de Quimica Orgànica Y Umymfor, Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, Buenos Aires, 1428, Argentina 
506 |2 openaire  |e Política editorial 
504 |a Russo, C.A., Gros, E.G., (1981) Phytochemistry, 20, p. 1763 
504 |a Ghini, A.A., Burton, G., Gros, E.G., (1982) Phytochemistry, 21, p. 605 
504 |a Russo, C.A., Gros, E.G., (1982) Phytochemistry, 21, p. 609 
504 |a Russo, C.A., Burton, G., Gros, E.G., (1983) Phytochemistry, 22, p. 71 
504 |a Russo, C.A., Gros, E.G., (1983) Phytochemistry, 22, p. 1839 
504 |a Albright, I.D., (1974) J. Org. Chem., 39, p. 1977 
504 |a Klein, P.D., Knight, J.D., (1965) J. Am. Chem. Soc., 87, p. 2657 
504 |a Adam, G., Huang, H.Th., (1980) Tetrahedron Lett., 21, p. 1931 
504 |a Schreiber, K., Adam, G., (1961) Experientia, 17, p. 13 
504 |a Toldy, L., (1958) Acta. Chim. Acad. Sci Hung., 16, p. 403 
504 |a Bukovits, G.J., Daller, D., ; Uhle, F.C., (1961) J. Am. Chem. Soc., 83, p. 1460 
520 3 |a The preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine was accomplished by oxydation of the unlabelled compound to tomatidone, exchange of the labile hydrogens by reaction with H20 and 3H2O on basic alumina and direct reduction of the labelled tomatidone to tomatidine. The efficiency of the procedure was checked by physical (1H and 13C NMR, MS) methods. Copyright © 1986 John Wiley & Sons, Ltd.  |l eng 
593 |a Departamento de Quimica Orgànica Y Umymfor, Facultad de Ciencias Exactas Y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, Buenos Aires, 1428, Argentina 
690 1 0 |a |2,4‐2H|‐TOMATIDINE 
690 1 0 |a |2,4‐3H|‐TOMATIDINE 
690 1 0 |a RADIOISOTOPE 
690 1 0 |a METHODOLOGY 
690 1 0 |a NONHUMAN 
690 1 0 |a PRIORITY JOURNAL 
690 1 0 |a THEORETICAL STUDY 
690 1 0 |a TOMATIDINE H 2 
690 1 0 |a TOMATIDINE H 3 
700 1 |a Gros, E.G. 
773 0 |d 1986  |g v. 23  |h pp. 109-112  |k n. 1  |p J. Label. Compd. Radiopharm.  |x 03624803  |w (AR-BaUEN)CENRE-1949  |t Journal of Labelled Compounds and Radiopharmaceuticals 
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856 4 0 |u https://doi.org/10.1002/jlcr.2580230114  |y DOI 
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