Copper speciation in soil time evolution and effect of clay amendment

Copper bioavailability, specially to plants, is strongly dependent on its chemical form, as for most metals. Copper-contaminated soil can be treated in situ by the addition of minerals such as Na-bentonite, which mixed with surface soil, can transform this pollutant to non-bioavailable forms. In thi...

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Otros Autores: Montenegro, Andrea C., Ferreyroa, Gisele V., Parolo, María E., Tudino, Mabel B., Lavado, Raúl Silvio, Molina, Fernando V.
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Lenguaje:Inglés
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Acceso en línea:http://ri.agro.uba.ar/files/intranet/articulo/2015montenegro.pdf
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024 |a 10.1007/s11270-015-2569-1 
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245 1 0 |a Copper speciation in soil   |b time evolution and effect of clay amendment 
520 |a Copper bioavailability, specially to plants, is strongly dependent on its chemical form, as for most metals. Copper-contaminated soil can be treated in situ by the addition of minerals such as Na-bentonite, which mixed with surface soil, can transform this pollutant to non-bioavailable forms. In this work, shelter experiments were conducted to study the time evolution of Cu speciation, in pristine soil as well as in amended one. A selective sequential extraction method was employed to determine the metal speciation in the samples. The results show that the major metal fraction is the organic matter-bound one, whereas the exchangeable fraction is very low, even the first day after Cu addition. The time evolution shows a slow decrease of the organic-bound Cu and a corresponding increase of the most stable mineral fractions. With the addition of Na-bentonite to copper-contaminated soil, the most stable mineral fractions increase whereas the organic-bound one decreases, showing essentially similar time dependence of the several metal fractions. Sodium bentonite could be effectively used for remediation of soils polluted with Cu. 
650 |2 Agrovoc  |9 26 
653 0 |a SEQUENTIAL SELECTIVE EXTRACTION 
653 0 |a AVAILABILITY 
653 0 |a BENTONITE 
653 0 |a HEAVY METALS 
653 0 |a SOIL POLLUTION 
700 1 |a Montenegro, Andrea C.  |9 70354 
700 1 |a Ferreyroa, Gisele V.  |9 67295 
700 1 |a Parolo, María E.  |9 70355 
700 1 |a Tudino, Mabel B.  |9 67749 
700 1 |9 24365  |a Lavado, Raúl Silvio 
700 1 |a Molina, Fernando V.  |9 37981 
773 |t Water, Air and Soil Pollution  |g vol.226, no.9 (2015), p.1-10, grafs., tbls. 
856 |u http://ri.agro.uba.ar/files/intranet/articulo/2015montenegro.pdf  |i En reservorio  |q application/pdf  |f 2015montenegro  |x MIGRADOS2018 
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