Breaking process 3 Dispersive forces 3 Dynamical analysis 3 Dynamical behaviors 3 Dynamics 3 Functional groups 3 Functionalized silica 3 Hydrogen 3 Hydrogen bonds 3 Hydrogen-bond formation 3 Hydrophobic pore 3 Hydroxyl groups 3 Hydroxylated surfaces 3 Liquid methanol 3 Liquids 3 Local perspective 3 Methanol 3 Molecular dynamics 3 Molecular dynamics simulations 3 Nanopores 3 Pore wall 3 Rotational dynamics 3 Rotational flow 3 Rotational motion 3 Silanol groups 3 Silica 3 Silica pores 3 Spatial ordering 3 Structure and dynamics 3 Surface state 3