Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles
Direct evidence is presented that the otherwise thermodynamically forbidden reduction of As(V) by conduction band electrons of the semiconductor can be driven in the dark by accumulated electrons stored in alcoholic TiO2 nanoparticles. Accumulation of electrons and participation in As(V) reduction w...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_97811380_v_n_p802_Levy |
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todo:paper_97811380_v_n_p802_Levy2023-10-03T16:43:01Z Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles Levy, I.K. Quici, N. Custo, G. Litter, M.I. Brusa, M. Aguirre, M.E. Grela, M.A. San Román, E. et al.; National Atomic Energy Commission (CNEA); National Research and Technology Council (CONICET); The Argentine Foundation of Nanotechnology; The National University of Buenos Aires (UBA); The National University of San Martin (UNSAM) Arsenic Magnetic resonance Nanoparticles Conduction band electrons TiO TiO2 nano-particles UV-vis spectrophotometry Electrons Direct evidence is presented that the otherwise thermodynamically forbidden reduction of As(V) by conduction band electrons of the semiconductor can be driven in the dark by accumulated electrons stored in alcoholic TiO2 nanoparticles. Accumulation of electrons and participation in As(V) reduction was directly followed by UV-vis spectrophotometry and by Electron Paramagnetic Resonance, detected as Ti(III) species. © 2014 Taylor & Francis Group. Fil:Levy, I.K. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Litter, M.I. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:San Román, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. CONF info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_97811380_v_n_p802_Levy |
| institution |
Universidad de Buenos Aires |
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I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Arsenic Magnetic resonance Nanoparticles Conduction band electrons TiO TiO2 nano-particles UV-vis spectrophotometry Electrons |
| spellingShingle |
Arsenic Magnetic resonance Nanoparticles Conduction band electrons TiO TiO2 nano-particles UV-vis spectrophotometry Electrons Levy, I.K. Quici, N. Custo, G. Litter, M.I. Brusa, M. Aguirre, M.E. Grela, M.A. San Román, E. et al.; National Atomic Energy Commission (CNEA); National Research and Technology Council (CONICET); The Argentine Foundation of Nanotechnology; The National University of Buenos Aires (UBA); The National University of San Martin (UNSAM) Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles |
| topic_facet |
Arsenic Magnetic resonance Nanoparticles Conduction band electrons TiO TiO2 nano-particles UV-vis spectrophotometry Electrons |
| description |
Direct evidence is presented that the otherwise thermodynamically forbidden reduction of As(V) by conduction band electrons of the semiconductor can be driven in the dark by accumulated electrons stored in alcoholic TiO2 nanoparticles. Accumulation of electrons and participation in As(V) reduction was directly followed by UV-vis spectrophotometry and by Electron Paramagnetic Resonance, detected as Ti(III) species. © 2014 Taylor & Francis Group. |
| format |
CONF |
| author |
Levy, I.K. Quici, N. Custo, G. Litter, M.I. Brusa, M. Aguirre, M.E. Grela, M.A. San Román, E. et al.; National Atomic Energy Commission (CNEA); National Research and Technology Council (CONICET); The Argentine Foundation of Nanotechnology; The National University of Buenos Aires (UBA); The National University of San Martin (UNSAM) |
| author_facet |
Levy, I.K. Quici, N. Custo, G. Litter, M.I. Brusa, M. Aguirre, M.E. Grela, M.A. San Román, E. et al.; National Atomic Energy Commission (CNEA); National Research and Technology Council (CONICET); The Argentine Foundation of Nanotechnology; The National University of Buenos Aires (UBA); The National University of San Martin (UNSAM) |
| author_sort |
Levy, I.K. |
| title |
Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles |
| title_short |
Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles |
| title_full |
Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles |
| title_fullStr |
Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles |
| title_full_unstemmed |
Dark reduction of As(V) by accumulated electrons stored in alcoholic TiO2 nanoparticles |
| title_sort |
dark reduction of as(v) by accumulated electrons stored in alcoholic tio2 nanoparticles |
| url |
http://hdl.handle.net/20.500.12110/paper_97811380_v_n_p802_Levy |
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