Distance-dependent electron transfer rate of immobilized redox proteins: A statistical physics approach

The electron transfer kinetics of redox proteins adsorbed on metal electrodes coated with self-assembled monolayers (SAMs) of mercaptanes shows an unusual distance-dependence. For thick SAMs, the experimentally measured electron transfer rate constant kexp obeys the behavior predicted by Marcus theo...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Georg, S., Kabuss, J., Weidinger, I.M., Murgida, D.H., Hildebrandt, P., Knorr, A., Richter, M.
Formato: JOUR
Materias:
Coated electrodes
Electron transfer kinetics
Electron transfer process
Electron transfer rates
Electron-transfer rate constants
High electric fields
Kinetic experiment
Marcus theory
Metal electrodes
Model proteins
Non-exponential behavior
Orientational distributions
Redox proteins
Sams
Saturation regime
Statistical average
Statistical physics
Theoretical models
Coated wire electrodes
Electric fields
Electrodes
Electron transitions
Electron tunneling
Rate constants
Self assembled monolayers
Proteins
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_15393755_v81_n4_p_Georg
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

Ejemplares similares

Ejemplares similares