Conformational and electronic effects on the regioselectivity of the glycosylation of different anomers of N-dimethylmaleoyl-protected glucosamine acceptors

In a previous paper (Bohn et al., Carbohydr. Res., 2007, 342, 2522) the relative O3/O4 reactivities of both α- and β-methyl glycosides of N-dimethylmaleoyl (DMM) glucosamine acceptors protected at O6 with three different groups were assessed by us, using two glycosyl donors. The α-anomers showed pre...

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Autores principales: Bohn, M.L., Colombo, M.I., Rúveda, E.A., Stortz, C.A.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_14770520_v6_n3_p554_Bohn
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