Rearrangement of 18-iodo- and 20-iodopregnanes mediated by iodosyl derivatives
Conversion of 20-acetoxy-18-iodopregn-4-en-3-one 1 to the 18-iodosyl derivative by MCPBA resulted in a Wagner–Meerwein-type rearrangement with regioselective migration of the C13–C17 bond to give, in high yield, an abeo-pregnane in which C-18 was incorporated into ring D. The rearranged steroid was...
Guardado en:
Autores principales: | Nicoletti, D., Ghini, A.A., Baggio, R.F., Garland, M.T., Burton, G. |
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Formato: | JOUR |
Materias: | |
Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_14727781_v1_n13_p1511_Nicoletti |
Aporte de: |
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