An electron-rich {RuNO} 6 complex: Trans-[Ru(DMAP) 4(NO)(OH)] 2+ - Structure and reactivity

The pseudo-octahedral nitrosyl species trans-[Ru(DMAP) 4(NO)(OH)] 2+ [1 2+, DMAP = 4-(dimethylamino)pyridine] was prepared by the reaction between [Ru(DMAP) 5(H 2O)] 2+ and NaNO 2 under mild conditions (room temperature, pH = 6-8), and precipitated with NaBF 4 or NaPF 6. Single-crystal X-ray diffrac...

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Detalles Bibliográficos
Autores principales:	Osa Codesido, N., De Candia, A.G., Weyhermüller, T., Olabe, J.A., Slep, L.D.
Formato:	JOUR
Materias:	Cyclic voltammetry Density functional calculations Electronic structure Nitrogen oxides Nitrosyl complexes Ruthenium
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_14341948_v_n27_p4301_OsaCodesido
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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