Near-critical and supercritical dilute solutions viewed from macroscopic and molecular-scale perspectives

Partial molar properties of dilute solutes in near-critical solvents exhibit a strong dependence on temperature and density which hinders the description of their behaviour under those conditions. We used the well-behaved Krichevskii function, J = (dp/dx)V,T supra infinity, to describe that region o...

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Detalles Bibliográficos
Autores principales: Fernández-Prini, R., Laura Japas, M., Marceca, E.
Formato: JOUR
Materias:
Critical behaviour
Intermolecular interactions
Krichevskii's function
Near-critical solvents
Solvation
Continuous exploration
Critical solution
Density dependence
Dilute solution
Partial molar properties
Super-critical
Supercritical solvents
Ternary solution
Phase transitions
Ternary systems
Solvents
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_08968446_v55_n2_p472_FernandezPrini
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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