Synthesis of D-galactofuranosyl-containing C-disaccharides
The C-disaccharide analogue of the sequence β-D-Galf-(1→3)-β-D-Glcp, an internal disaccharide of the capsular polysaccharide of Klebsiella K14 was synthesized by radical macrocyclization of temporarily tethered monosaccharides. The α-difluoro-C-analogue was obtained in three steps from D-galactono-1...
| Autores principales: | , , , , |
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| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_07328303_v19_n1_p1_Kovensky |
| Aporte de: |
| Sumario: | The C-disaccharide analogue of the sequence β-D-Galf-(1→3)-β-D-Glcp, an internal disaccharide of the capsular polysaccharide of Klebsiella K14 was synthesized by radical macrocyclization of temporarily tethered monosaccharides. The α-difluoro-C-analogue was obtained in three steps from D-galactono-1,4-lactone. |
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