The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]

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The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordinat...

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Autores principales: Baggio, R., Garland, M.T., Perec, M.
Formato: JOUR
Materias:
Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_01082701_v52_n4_p823_Baggio2023-10-03T14:57:46Z The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br] Baggio, R. Garland, M.T. Perec, M. Bromine compounds Cadmium compounds Chlorine compounds Crystal atomic structure Molecular structure Spectroscopic analysis Cadmium halide bis(diethyldithiocarbamate) complexes Isomorphous compounds Mononuclear complexes Organometallics The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordination spheres of the types S4Cl and S4Br, respectively. The central Cd atom is linked to four S atoms and two bidentate dithiocarbamate ligands and to the halide atom. The resulting Cd-atom coordination geometry is halfway between trigonal bipyrimidal and square pyramidal. Principal dimensions include: Cd-S 2.573 (1)-2.682 (1) in (1) and 2.571 (3)-2.736 (2) Å in (2); Cd-Cl and Cd-Br 2.462 (1) and 2.626 (1) Å, respectively. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
spellingShingle Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
Baggio, R.
Garland, M.T.
Perec, M.
The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
topic_facet Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
description The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordination spheres of the types S4Cl and S4Br, respectively. The central Cd atom is linked to four S atoms and two bidentate dithiocarbamate ligands and to the halide atom. The resulting Cd-atom coordination geometry is halfway between trigonal bipyrimidal and square pyramidal. Principal dimensions include: Cd-S 2.573 (1)-2.682 (1) in (1) and 2.571 (3)-2.736 (2) Å in (2); Cd-Cl and Cd-Br 2.462 (1) and 2.626 (1) Å, respectively.
format JOUR
author Baggio, R.
Garland, M.T.
Perec, M.
author_facet Baggio, R.
Garland, M.T.
Perec, M.
author_sort Baggio, R.
title The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_short The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_full The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_fullStr The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_full_unstemmed The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_sort five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [pph4][cd(s2cnet2)2cl] and [pph4][cd(s2cnet2)2br]
url http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
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