Synthesis of 17a-alkyl- and 17a-aryl-3β-acetoxy- and 3β-methoxy-17a-aza-d-homoandrost-5-en-17-one

A short and efficient preparation of 17a-methyl-, 17a-ethyl-, 17a-allyl-, and 17a-benzyl-3β-acetoxy-17a-aza-d-homoandrost-5-en-17-one, as well as 17a-methyl-, 17a-ethyl-, and 17a-allyl-3β-methoxy-17a-aza-s-homoandrost-5-en-17-one from the corresponding androsten-17-one derivatives is described. (Ste...

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Detalles Bibliográficos
Autores principales: Revelli, G.A., Gros, E.G.
Formato: JOUR
Materias:
17a-aza-d-homoandrost-5-en-17-one derivatives
13C nuclear magnetic resonance spectra
1H nuclear magnetic resonance spectra
azasteroids
synthesis
17a allyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a allyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
17a benzyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a ethyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a ethyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
17a methyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a methyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
3beta acetoxy 17a aza d homoandrost 5 en 17 one
3beta methoxy 17a aza d homoandrost 5 en 17 one
azasteroid
unclassified drug
article
carbon nuclear magnetic resonance
drug structure
drug synthesis
mass spectrometry
proton nuclear magnetic resonance
Androstenols
Azasteroids
Magnetic Resonance Spectroscopy
Molecular Structure
Support, Non-U.S. Gov't
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_0039128X_v58_n4_p181_Revelli
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:A short and efficient preparation of 17a-methyl-, 17a-ethyl-, 17a-allyl-, and 17a-benzyl-3β-acetoxy-17a-aza-d-homoandrost-5-en-17-one, as well as 17a-methyl-, 17a-ethyl-, and 17a-allyl-3β-methoxy-17a-aza-s-homoandrost-5-en-17-one from the corresponding androsten-17-one derivatives is described. (Steroids 58:181-184, 1993). © 1993.

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