The Wohl Reaction Applied to Some Benzoylated Aldononitriles

Hexa-O-benozyl-D-glycerogulo-heptonomtrile (III), hexa-O-benzoyl-D-glycero-L-mareno-heptononitrile (IV), D-glycero-D-galacto-heptose oxime (V), and, from this last compound, hexa,-O-benzoyl-D-glycero-D-galacto-heptononitrile (VI) were prepared; these nitriles were treated with methanolic ammonia. Fr...

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Autores principales: Deferrari, J.O., Matsuhiro, B.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00223263_v31_n3_p905_Deferrari
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Sumario:Hexa-O-benozyl-D-glycerogulo-heptonomtrile (III), hexa-O-benzoyl-D-glycero-L-mareno-heptononitrile (IV), D-glycero-D-galacto-heptose oxime (V), and, from this last compound, hexa,-O-benzoyl-D-glycero-D-galacto-heptononitrile (VI) were prepared; these nitriles were treated with methanolic ammonia. From III, l,l-bis(ben-zamido)-l-deoxy-D-glucitol,. N-benzoyl-β-D-glucopyranosylamine, and D-glucose were obtained. From IV, 1,1-bis(benzamido)-l-deoxy-D-galactitol, N-benzoyl-β-D-galactopyranosylamine, and D-galactose were obtained. From VI, l,l-bis(benzamido)-l-deoxy-D-mannitol, Arbenzoyl-β-D-mannopyranosylamine, and D-mannose were obtained. © 1966, American Chemical Society. All rights reserved.