The Reaction of Ammonia with Acylated Disaccharides. IV. The Structure of the 1,1-Bis(acetamido)-1-deoxyaldobiitols
By means of methylation and hydrolysis techniques it was demonstrated that the 1,1-bis(acetamido)-1-deoxycellobiitol, the 1,1-bis(acetamido)-1-deoxylactitol, and the 1,1-bis(acetamido)-1-deoxymaltitol obtained by the reaction of ammonia upon the corresponding acetylated aldobioses have an acyclic st...
Guardado en:
| Autores principales: | , |
|---|---|
| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00223263_v30_n6_p2007_Deferrari |
| Aporte de: |
| Sumario: | By means of methylation and hydrolysis techniques it was demonstrated that the 1,1-bis(acetamido)-1-deoxycellobiitol, the 1,1-bis(acetamido)-1-deoxylactitol, and the 1,1-bis(acetamido)-1-deoxymaltitol obtained by the reaction of ammonia upon the corresponding acetylated aldobioses have an acyclic structure in the nitrogenated moiety. The separation of a mixture of 2,3,5,6-tetra-O-methyl-D-glucose and 2,3,4,6-tetra-O-methyl-D-glucose by gas-liquid and by anion-exchange resin chromatographies is described. © 1965, American Chemical Society. All rights reserved. |
|---|