The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation
1. By the action of methanolic ammonia on the α- and β-isomers of pentabenzoyl-d-glucose, d-glucose dibenzamide is obtained in almost the same yield. 2. When hexaacetyl-d-gluco-d-ido-heptonic nitrile is treated with methanolic ammonia, N-acetyl-d-glucofuranosylamine is produced, in a yield similar t...
| Autores principales: | , |
|---|---|
| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00223263_v17_n8_p1087_Deulofeu |
| Aporte de: |
| Sumario: | 1. By the action of methanolic ammonia on the α- and β-isomers of pentabenzoyl-d-glucose, d-glucose dibenzamide is obtained in almost the same yield. 2. When hexaacetyl-d-gluco-d-ido-heptonic nitrile is treated with methanolic ammonia, N-acetyl-d-glucofuranosylamine is produced, in a yield similar to that obtained from the epimer, hexaacetyl-d-gluco-d-gulo-heptonic nitrile. 3. A discussion is given of the mechanism of the reaction. © 1952, American Chemical Society. All rights reserved. |
|---|