Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series

Three new lanthanide oxydiacetate compounds have been prepared and their structures determined by single crystal X-ray methods: {[Ln2(oda)3(H2O)2]·5H2O}(n) (Ln = Eu, Gd) and [Eu(oda)(Hoda)(H2O)]·2H2O. The former are orthorhombic and Ama2, with LnO8 and LnO9 cores bridged by anti-anti carboxylate lig...

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Autores principales: Aramendia, P.F., Baggio, R., Garland, M.T., Perec, M.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00201693_v303_n2_p306_Aramendia
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spelling todo:paper_00201693_v303_n2_p306_Aramendia2023-10-03T14:17:16Z Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series Aramendia, P.F. Baggio, R. Garland, M.T. Perec, M. Crystal structures Lanthanide complexes Luminescence acetoacetic acid europium gadolinium lanthanide article chemical structure crystal structure ligand binding luminescence solid state X ray analysis Three new lanthanide oxydiacetate compounds have been prepared and their structures determined by single crystal X-ray methods: {[Ln2(oda)3(H2O)2]·5H2O}(n) (Ln = Eu, Gd) and [Eu(oda)(Hoda)(H2O)]·2H2O. The former are orthorhombic and Ama2, with LnO8 and LnO9 cores bridged by anti-anti carboxylate ligands and the latter is mononuclear containing a EuO9 core. Luminescence spectra of the europium complexes in the solid state are presented. (C) 2000 Elsevier Science S.A. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00201693_v303_n2_p306_Aramendia
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Crystal structures
Lanthanide complexes
Luminescence
acetoacetic acid
europium
gadolinium
lanthanide
article
chemical structure
crystal structure
ligand binding
luminescence
solid state
X ray analysis
spellingShingle Crystal structures
Lanthanide complexes
Luminescence
acetoacetic acid
europium
gadolinium
lanthanide
article
chemical structure
crystal structure
ligand binding
luminescence
solid state
X ray analysis
Aramendia, P.F.
Baggio, R.
Garland, M.T.
Perec, M.
Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series
topic_facet Crystal structures
Lanthanide complexes
Luminescence
acetoacetic acid
europium
gadolinium
lanthanide
article
chemical structure
crystal structure
ligand binding
luminescence
solid state
X ray analysis
description Three new lanthanide oxydiacetate compounds have been prepared and their structures determined by single crystal X-ray methods: {[Ln2(oda)3(H2O)2]·5H2O}(n) (Ln = Eu, Gd) and [Eu(oda)(Hoda)(H2O)]·2H2O. The former are orthorhombic and Ama2, with LnO8 and LnO9 cores bridged by anti-anti carboxylate ligands and the latter is mononuclear containing a EuO9 core. Luminescence spectra of the europium complexes in the solid state are presented. (C) 2000 Elsevier Science S.A.
format JOUR
author Aramendia, P.F.
Baggio, R.
Garland, M.T.
Perec, M.
author_facet Aramendia, P.F.
Baggio, R.
Garland, M.T.
Perec, M.
author_sort Aramendia, P.F.
title Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series
title_short Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series
title_full Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series
title_fullStr Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series
title_full_unstemmed Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series
title_sort novel europium and gadolinium compounds in the lanthanide(iii) oxydiacetate series
url http://hdl.handle.net/20.500.12110/paper_00201693_v303_n2_p306_Aramendia
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AT garlandmt noveleuropiumandgadoliniumcompoundsinthelanthanideiiioxydiacetateseries
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