Reduction of the NO+ ligand in the pentacyanonitrosylosmate(II) ion

The reversible reduction of [Os(CN)5(NO)]2-, the osmium analog of the nitroprusside ion, has been studied by spectroelectrochemical techniques (IR, UV-Vis, EPR). The strong shift of the nitrosyl stretching band from 1850 to 1560 cm-1 (in acetonitrile) already indicates nitrosyl ligand-centered reduc...

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Detalles Bibliográficos
Autores principales:	Baumann, F., Kaim, W., M. Baraldo, L., Slep, L.D., Olabe, J.A., Fiedler, J.
Formato:	JOUR
Materias:	Cyanide complexes EPR Nitrosyl complexes Osmium complexes Spectroelectrochemistry
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00201693_v285_n1_p129_Baumann
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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