Widely differing photochemical behavior in related octahedral {Ru-NO} 6 compounds: Intramolecular redox isomerism of the excited state controlling the photodelivery of NO

trans-[(NC)Ru(py) 4(μ-CN)Ru(py) 4(NO)] 3+ (py = pyridine) is a stable species in aqueous solution. It displays an intense absorption in the visible region of the spectrum (λ max = 518 nm; ε max = 6100 M -1 cm -1), which turns this compound into a promising agent for the photodelivery of NO. The quan...

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Detalles Bibliográficos
Autores principales:	De Candia, A.G., Marcolongo, J.P., Etchenique, R., Slep, L.D.
Formato:	JOUR
Materias:	nitric oxide organometallic compound ruthenium article chemical structure chemistry conformation drug design electron oxidation reduction reaction photochemistry quantum theory stereoisomerism Drug Design Electrons Models, Molecular Molecular Conformation Nitric Oxide Organometallic Compounds Oxidation-Reduction Photochemical Processes Quantum Theory Ruthenium Stereoisomerism
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00201669_v49_n15_p6925_DeCandia
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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