Kinetics and mechanism of ligand interchange in pentacyano-L-osmate(II) complexes (L = H2O, NH3, N-heterocyclic ligands

The new complex, K3[Os(CN)5NH3]·2H2O, a convenient precursor for the pentacyano-L-osmate(II) series, was prepared and characterized by chemical analysis, cyclic voltammetry, and IR and UV-vis spectroscopies. By controlled aquation in weakly acidic medium, the [Os(CN)5H2O]3- ion was generated. Weak a...

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Detalles Bibliográficos
Autores principales:	Slep, L.D., Alborés, P., Baraldo, L.M., Olabe, J.A.
Formato:	JOUR
Materias:	ammonia heterocyclic compound iron derivative isonicotinamide isonicotinic acid ligand nitrile osmium derivative pyrazine derivative pyridine derivative ruthenium derivative water acidity article chemical analysis chemical reaction kinetics cyclic potentiometry dissociation enthalpy entropy infrared spectroscopy synthesis ultraviolet spectroscopy
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00201669_v41_n1_p114_Slep
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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