Reaction of ammonia with some acetylated and benzoylated monosaccharides. Part XI. Intramolecular migration of O-benzoyl groups in the partial ammonolysis of penta-O-benzoyl-D-glucoses
By the use of three differently labeled penta-O-benzoyl-D-glucopyranoses, it was possible to detect a partial, benzoyl migration from O-4 to O-6 during the ammonolysis of penta-benzoyl-D-O-glucopyranose in isopropyl alcohol. When the same reaction was applied to a penta-O-benzoyl-aldehydo-D-glucose...
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| Autores principales: | , , , |
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00086215_v4_n1_p1_Lezerovich |
| Aporte de: |
| Sumario: | By the use of three differently labeled penta-O-benzoyl-D-glucopyranoses, it was possible to detect a partial, benzoyl migration from O-4 to O-6 during the ammonolysis of penta-benzoyl-D-O-glucopyranose in isopropyl alcohol. When the same reaction was applied to a penta-O-benzoyl-aldehydo-D-glucose derivative, a partial migration of a benzoyl group from O-2 to O-6 was also encountered. © 1967. |
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