Synthesis of furanose derivatives of 3-deoxy-D-erythro-2-hexulosonic acid and their 3-bromo and 3-deuterio analogs

Methanolysis of 2,4,6-tri-O-benzoyl-2,3-dibromo-3-deoxy-D-altrono-1,5-lactone gave methyl 3-bromo-3-deoxy-2,4,6-tri-O-benzoyl-α-D-ribo-hex-2-ulofuranosonate (3) and the anomeric mixture of the analogous 4,6-di-O-benzoyl derivative, having HO-2 free. Compound 3 was subjected to debromination with tri...

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Detalles Bibliográficos
Autores principales:	Di Nardo, C., Varela, O.
Formato:	JOUR
Materias:	3-Deoxy-D-erythro-2-hexulosonic acid 3-Deuterio derivatives Aldonolactones Furanose derivatives of 3-deoxy-2-hexulosonic acid Methanolysis 3 deoxy dextro erythro 2 hexulosonic acid derivative furan derivative lactone derivative methyl 3 bromo 3 deoxy 2,4,6 tri o benzoyl alpha dextro ribo hex 2 ulofuranosonic acid methyl 3 bromo 3 deoxy 4,6 di o benzoyl alpha,beta dextro ribo hex 2 ulofuranosonic acid methyl 3 deoxy 3 deutero 2,4,6 tri o benzoyl alpha dextro arabino hex 2 ulofuranosonic acid methyl 3 deoxy 3 deutero 2,4,6 tri o benzoyl alpha dextro ribo hex 2 ulofuranosonic acid nitrile tributyltin unclassified drug article carbohydrate synthesis chemical structure debromination degradation priority journal reaction analysis structure analysis Bacteria Furans Gluconates Ketoses Sugar Acids Support, Non-U.S. Gov't
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00086215_v328_n4_p605_DiNardo
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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