A surprisingly stable S-nitrosothiol complex

In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Perissinotti, L.L., Estrin, D.A., Leitus, G., Doctorovich, F.
Formato: JOUR
Materias:
s nitrosothiol
article
complex formation
crystal structure
density functional theory
infrared spectroscopy
proton nuclear magnetic resonance
synthesis
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00027863_v128_n8_p2512_Perissinotti
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully characterized by FTIR, 1H NMR, and ESI-MS. To our knowledge this is the first example of a coordinated S-nitrosothiol that has been isolated. Copyright © 2006 American Chemical Society.

Ejemplares similares