Structural and spectroscopic evidence of strong electronic delocalization through a cyanido bridge in a mixed-valence Os-Ru complex

We report the properties of a trinuclear cyanido-bridged complex, trans-(dmap)4RuII(Âμ-NC)OsIII(CN) 524- [14-; dmap = 4-(dimethylamino)pyridine], whose structure and electronic and vibrational spectra present strong evidence of partial redox states for the three metal ions, an unprecedented feature...

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Detalles Bibliográficos
Publicado:	2010
Materias:	Cyanido bridge Delocalization Mixed-valent compounds Osmium Ruthenium
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14341948_v_n36_p5613_Rossi http://hdl.handle.net/20.500.12110/paper_14341948_v_n36_p5613_Rossi
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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