Synthesis, characterization, X-ray crystal structure, DFT calculation, DNA binding, and antimicrobial assays of two new mixed-ligand copper(II) complexes

Two new Cu(II) complexes, [Cu(L)(phen)] (1), [Cu(L)(bipy)] (2), where L2- = (3-methoxy-2oxidobenzylidene)benzohydrazidato, phen = 1,10 phenanthroline, and bipy = 2,2′ bipyridine, were prepared and fully characterized using elemental analyses, FT-IR, molar conductivity, and electronic spectra. The st...

Descripción completa

Guardado en:

Detalles Bibliográficos
Publicado:	2015
Materias:	Antimicrobial activity Crystal structure Cu(II) complex DFT calculation DNA binding Hydrazone Schiff base Chelation Complexation Computation theory Coordination reactions Cyclic voltammetry Density functional theory DNA Functional groups Microorganisms Synthesis (chemical) X ray diffraction Anti-microbial activity Cu complexes Hydrazones Schiff-base Copper compounds 2,2' bipyridine antiinfective agent coordination compound copper intercalating agent phenanthroline derivative animal Bacterial Infections bacterium chemical structure chemistry drug effects fungus human metabolism Mycoses salmonine X ray crystallography 2,2'-Dipyridyl Animals Anti-Infective Agents Bacteria Coordination Complexes Copper Crystallography, X-Ray Fungi Humans Intercalating Agents Models, Molecular Phenanthrolines Salmon
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_13861425_v142_n_p410_Ebrahimipour http://hdl.handle.net/20.500.12110/paper_13861425_v142_n_p410_Ebrahimipour
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

Ejemplares similares

Synthesis, characterization, X-ray crystal structure, DFT calculation, DNA binding, and antimicrobial assays of two new mixed-ligand copper(II) complexes
por: Ebrahimipour, S.Y., et al.

Synthesis, crystal structure and cytotoxicity assays of a copper(II) nitrate complex with a tridentate ONO acylhydrazone ligand: spectroscopic and theoretical studies of the complex and its ligand
por: Burgos López, Yacelis, et al.
Publicado: (2019)

X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes
por: Baggio, Ricardo F., et al.
Publicado: (2000)

X-ray study on the nickel(II)-oxydiacetic system and its 1,10-phenanthroline and 2,2':6',2'' terpyridine complexes
por: Baggio, R., et al.

Two solvatomorphic forms of a copper complex formulated as Cu( 1)(ClO4)2-1.2H2O and Cu(1)(ClO4)2, where 1 is 3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane
por: Suarez, Sebastian, et al.
Publicado: (2013)

Two solvatomorphic forms of a copper complex formulated as Cu( 1)(ClO4)2-1.2H2O and Cu(1)(ClO4)2, where 1 is 3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane
por: Nath, B.C., et al.
Publicado: (2013)

Two solvatomorphic forms of a copper complex formulated as Cu( 1)(ClO4)2-1.2H2O and Cu(1)(ClO4)2, where 1 is 3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane
por: Nath, B.C., et al.

Two solvatomorphic forms of a copper complex formulated as Cu( 1)(ClO4)2-1.2H2O and Cu(1)(ClO4)2, where 1 is 3,10-C-meso-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane
por: Nath, B.C., et al.
Publicado: (2013)

Structure and magnetic properties of binuclear Cu 2 (O 2 CCH=CHCH 3 ) 4 (DMF) 2 : A carboxylate-bridged Cu(II) spin dimer
Publicado: (2000)

Structure and magnetic properties of binuclear Cu 2 (O 2 CCH=CHCH 3 ) 4 (DMF) 2 : A carboxylate-bridged Cu(II) spin dimer
por: Schlam, R.F., et al.

Synthesis, Crystal Structure, Spectroscopic Characterization, DFT Calculations and Cytotoxicity Assays of a New Cu(II) Complex with an Acylhydrazone Ligand Derived from Thiophene
por: Rodríguez, María Rosa, et al.
Publicado: (2021)

Structural characterization of the mesophases exhibited by dicopper and diruthenium trialkyloxybenzoates
por: Chaia, Zulema Débora, et al.
Publicado: (1999)

Structural characterization of the mesophases exhibited by dicopper and diruthenium trialkyloxybenzoates
por: Chaia, Z., et al.

Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines
Publicado: (2005)

Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines
por: Doctorovich, F., et al.

Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
por: Suarez, Sebastian, et al.
Publicado: (2013)

Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
por: Yasmin, S., et al.
Publicado: (2013)

Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
por: Yasmin, S., et al.

Three transition-metal complexes with the macrocyclic ligand meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L): [Cu(ClO4)2(L)], [Zn(NO3)2(L)] and [CuCl(L)(H2O)]Cl
por: Yasmin, S., et al.
Publicado: (2013)

Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of aquadichlorido{N- [(pyridin-2-yl)methylidene]aniline}copper(II) monohydrate
por: Molano, Miguel F., et al.
Publicado: (2020)

Pyrophosphate-bridged CuII chain magnet: {[Na 3Cu(P2O7)(NO3)]•3H 2O}n
por: Perec, Mireille
Publicado: (2010)

Pyrophosphate-bridged CuII chain magnet: {[Na 3Cu(P2O7)(NO3)]•3H 2O}n
por: Sartoris, R.P., et al.

Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
por: Perec, Mireille
Publicado: (2011)

Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
por: Perec, M., et al.

Synthesis and characterization of a series of isoniazid hydrazones : Spectroscopic and theoretical study
por: Ferraresi Curotto, Verónica, et al.
Publicado: (2017)

Structural, electrochemical characterization and SOD mimic activities of 1D chain or 3D network encouraged by unique μ 2 -bridging by adipate ion in mixed ligand complexes containing α-diimine as auxiliary ligand
Publicado: (2012)

Structural, electrochemical characterization and SOD mimic activities of 1D chain or 3D network encouraged by unique μ 2 -bridging by adipate ion in mixed ligand complexes containing α-diimine as auxiliary ligand
por: Siddiqi, Z.A., et al.

Europium(III) and terbium(III) trans-2-butenoates: Syntheses, crystal structures, and properties
por: Barja, Beatriz Carmen, et al.
Publicado: (2003)

Europium(III) and terbium(III) trans-2-butenoates: Syntheses, crystal structures, and properties
por: Barja, B., et al.

Crystallography and the liquid crystal phase: a new approach to structural studies on a thermo-tropic smectic Schiff base
Publicado: (2018)

Crystallography and the liquid crystal phase: a new approach to structural studies on a thermo-tropic smectic Schiff base
por: Piro, O.E., et al.

Kinetic and equilibrium adsorption of two post-harvest fungicides onto copper-exchanged montmorillonite: synergic and antagonistic effects of both fungicides’ presence
por: Gamba, Martina, et al.
Publicado: (2018)

A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
Publicado: (1999)

A dinuclear copper(II) complex involving monoatomic O-carboxylate bridging and Cu-S(thioether) bonds: [Cu(tda)(phen)]2 · H2tda (tda=thiodiacetate, phen=phenanthroline)
por: Baggio, R., et al.

Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
por: Baggio, Ricardo F., et al.
Publicado: (2001)

Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
por: Rizzi, A., et al.

Single crystal EPR study of the dinuclear Cu(II) complex [Cu(tda)(phen)]2·H2tda (tda = Thiodiacetate, phen = Phenanthroline): Influence of weak interdimeric magnetic interactions
por: Perec, Mireille, et al.
Publicado: (2010)

Single crystal EPR study of the dinuclear Cu(II) complex [Cu(tda)(phen)]2·H2tda (tda = Thiodiacetate, phen = Phenanthroline): Influence of weak interdimeric magnetic interactions
por: Neuman, N.I., et al.

Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)
Publicado: (2003)

Solid state coordination chemistry of pyridinedicarboxylic acid isomers. III Synthesis and crystal structures of complexes of Zn and Ni with lutidinic acid (lutidinic = 2,4-pyridinedicarboxylic)
por: Sileo, E.E., et al.