Reduction of the NO+ ligand in the pentacyanonitrosylosmate(II) ion

The reversible reduction of [Os(CN)5(NO)]2-, the osmium analog of the nitroprusside ion, has been studied by spectroelectrochemical techniques (IR, UV-Vis, EPR). The strong shift of the nitrosyl stretching band from 1850 to 1560 cm-1 (in acetonitrile) already indicates nitrosyl ligand-centered reduc...

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Detalles Bibliográficos
Publicado:	1999
Materias:	Cyanide complexes EPR Nitrosyl complexes Osmium complexes Spectroelectrochemistry
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v285_n1_p129_Baumann http://hdl.handle.net/20.500.12110/paper_00201693_v285_n1_p129_Baumann
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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