Benzoyl derivatives of d-gluconolactones and their reaction with alcohols
Benzoylation of d-glucono-1,4-lactone and d-glucono-1,5-lactone afforded the corresponding tetra-O-benzoyl derivatives. They showed the optical rotation and i.r. spectral absorption characteristic for 1,4 or 1,5-lactones, respectively. Opening of the lactone ring was effected by treatment with alcoh...
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| Autores principales: | , , |
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| Publicado: |
1970
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v13_n1_p9_deLederkremer http://hdl.handle.net/20.500.12110/paper_00086215_v13_n1_p9_deLederkremer |
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| Sumario: | Benzoylation of d-glucono-1,4-lactone and d-glucono-1,5-lactone afforded the corresponding tetra-O-benzoyl derivatives. They showed the optical rotation and i.r. spectral absorption characteristic for 1,4 or 1,5-lactones, respectively. Opening of the lactone ring was effected by treatment with alcohols to give tetra-O-benzoyl-d-gluconates having an unesterified hydroxyl group at C-4 or C-5, respectively. © 1970. |
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