Complex potentiodynamic response of silver in alkaline Electrolytes in the potential range of the Ag/Ag2O Couple
The potentiodynamic behaviour of Ag in 0.1 <i>M</i> NaOH in the potential range of Ag<sub>2</sub>O electroformation is investigated through the application of different potential/time perturbation programmes. The splitting of the electroreduction profile which is produced und...
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| Autores principales: | , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
1982
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/84593 |
| Aporte de: |
| Sumario: | The potentiodynamic behaviour of Ag in 0.1 <i>M</i> NaOH in the potential range of Ag<sub>2</sub>O electroformation is investigated through the application of different potential/time perturbation programmes. The splitting of the electroreduction profile which is produced under well-defined perturbation conditions and the shift of the Ag<sub>2</sub>O electroreduction <i>E/i</i> profile under a constant charge condition, suggest that ageing-type processes are involved in the overall electrochemical reaction. These processes are related to a probable dehydration of the Ag<sub>2</sub>O multilayer. |
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